33630-76-1Relevant academic research and scientific papers
The reductive dimerization of some 1,3-dienes and of 1,3,5-cycloheptatriene in the presence of trimethylchlorosilane: a DFT investigation
Aouf, Chahinez,El Abed, Douniazad,Giorgi, Michel,Santelli, Maurice
experimental part, p. 5563 - 5570 (2009/12/04)
Treatment of 1,3-dienes and 1,3,5-cycloheptatriene by chlorotrimethylsilane in the presence of wire of lithium led mainly to reductive dimerization with formation of bis(allylsilane) derivatives. Bis-silyl compounds obtained: from 1,3-butadiene, 1,8-bis(t
REACTIONS OF TRIMETHYLSILYLCYCLOPENTADIENE DERIVATIVES WITH TITANIUM, NIOBIUM, AND TANTALUM HALIDES
Cardoso, Ana M.,Clark, Robin J. H.,Moorhause, Stephen
, p. 1156 - 1160 (2007/10/02)
The use of trimethylsilyl derivatives as effective reagents for the new or improved syntheses of complexes of the early transition metals is described.Improved routes, involving the use of trimethylsilylcyclopentadiene, are described for the syntheses of , , , , and (cp=cyclopentadienyl).Routes, involving the use of bis(trimethylsilyl)cyclopentadiene, are described for the syntheses of the analogous complexes , where X=Cl, Br, or I.The reactions of , , and with a variety of bidentate ligands are described.The Lewis acidity of these titanium compounds is much reduced from that of the parent tetrahalides and only two adducts have been positively identified: these are *phen (phen=o-phenanthroline) and *pdma (pdma=o-phenylenebisdimethylarsine).
