336867-79-9

Basic information

• Product Name: methyl (Z)-3-phenylthio-2-nonenoate
• Synonyms: methyl (Z)-3-phenylthio-2-nonenoate
• CAS NO: 336867-79-9
• Molecular Weight: 278.415
• Mol File: 336867-79-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl (Z)-3-phenylthio-2-nonenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (Z)-3-phenylthio-2-nonenoate(336867-79-9)
• EPA Substance Registry System: methyl (Z)-3-phenylthio-2-nonenoate(336867-79-9)

Safety Data

• Hazardous Substances Data: 336867-79-9(Hazardous Substances Data)

Upstream product

• 629-05-0 n-octyne 
• 3186-52-5 O-methyl-S-phenyl thiolcarbonate 
• 111-80-8 methyl non-2-ynoate 
• 108-98-5 thiophenol 

Relevant articles and documents

Sulfonium Ylides by (3+2) Cycloaddition of Arynes with Vinyl Sulfides: Stereoselective Synthesis of Highly Substituted Alkenes

The reaction of in situ generated arynes with vinyl sulfides provides benzannulated sulfonium ylides in a (3+2) cycloaddition. Trapping of the intermediate ylides with electrophiles (proton transfer or a second aryne addition) and subsequent β-elimination give rise to di-, tri-, or tetrasubstituted alkenes with high stereoselectivity. Experimental studies and DFT calculations provide insight into the mechanisms of these cascade reactions.