3186-52-5Relevant academic research and scientific papers
Cu-Catalyzed Oxidative Thioesterification of Aroylhydrazides with Disulfides
Xie, Shimin,Su, Lebin,Mo, Min,Zhou, Wang,Zhou, Yongbo,Dong, Jianyu
, p. 739 - 749 (2021/01/09)
An alternative thioesterification reaction via copper-catalyzed oxidative coupling of readily available aroylhydrazides with disulfides is developed, in which oxidative expulsion of N2 overcomes the activation barrier between the carboxylic acid derivativ
Convenient route to thiocarbonates from alcohols, thiols, and triphosgene
Movassagh, Barahman,Soleiman-Beigi, Mohammad
experimental part, p. 3467 - 3471 (2011/02/22)
An efficient and simple one-pot, three-component procedure has been introduced for the preparation of various thiocarbonates from thiols, alcohols, and triphosgene in dichloromethane. Copyright Taylor & Francis Group, LLC.
A new method for synthesis of S-aryl-O-alkyl thiolcarbonates: Selenium-catalyzed reaction of alcohols with carbon monoxide and diaryl disulfides
Nishiyama, Yutaka,Maehira, Ken,Nakase, Junko,Sonoda, Noboru
, p. 7415 - 7417 (2007/10/03)
A unique catalytic ability of selenium has been developed. When alcohols were allowed to react with diaryl disulfides in the presence of a catalytic amount of selenium under a pressurized carbon monoxide, S-aryl-O-alkyl thiolcarbonates were obtained in moderate to good yields.
(Alkylthio)- and (phenylthio)methoxycarbenes from oxadiazolines
Er,Pole,Warkentin
, p. 1480 - 1489 (2007/10/03)
Four 2-methoxy-5,5-dimethyl-Δ3-1,3,4-oxadiazolines bearing an alkylthio or arylthio group at C2 were prepared. The oxadiazolines undergo thermolysis at 60-80 °C in solution to afford the corresponding oxythiocarbene intermediates. In the absence of carbene traps, dimers of the carbenes were formed. The carbenes were trapped with ethyl crotonate, with dichloromaleic anhydride, with dimethyl acetylenedicarboxylate, and with phenyl isocyanate. Phenyl isocyanate traps methoxy(methylthio)carbene to form two types of adducts, both fundamentally different from the product obtained from reaction of dimethoxycarbene with phenyl isocyanate. All of the adducts have structures consistent with nucleophilic behaviour of the carbenes.
Acyl transfer in o-hydroxybenzenethiol
McKinnon, David M.
, p. 2761 - 2764 (2007/10/02)
o-Hydroxybenzenethiol reacts with one equivalent of acetic anhydride to give a mixture of starting material, diacetylated material, and O- or S-monoacetylated products as determined by nmr.The same products are obtained by equilibration of a mixture of o-
