33732-71-7Relevant academic research and scientific papers
Evaluation of the β value of the phenylene unit by probing exchange interaction between two nitroxides
Higashiguchi, Kenji,Yumoto, Koji,Matsuda, Kenji
supporting information; experimental part, p. 5284 - 5286 (2011/02/24)
Oligophenylene molecular rods with bicyclo[2.2.2]octane having two nitronyl nitroxide radicals were synthesized to investigate the decay constant of p-phenylene. By the measurement and simulation of the ESR spectra of the biradicals with different rod len
Synthesis of molecular motors incorporating para-phenylene-conjugated or bicyclo[2.2.2]octane-insulated electroactive groups
Vives, Guillaume,Gonzalez, Alexandre,Jaud, Joel,Launay, Jean-Pierre,Rapenne, Gwenael
, p. 5622 - 5631 (2008/02/13)
The insulating role of the bicyclo[2.2.2]octane fragment has been theoretically evaluated by comparing the electronic coupling parameter (V ab) in 1,4-bis(ferrocenyl)benzene (1) and 1,4-bis(ferrocenyl) bicyclo[2.2.2]octane (2). The geometries w
Synthesis and intramolecular charge separation of fixed-distance triads consisting of zinc porphyrin, metal-free porphyrin, and electron-accepting diimide moiety
Osuka,Zhang,Maruyama,Ohno,Nozaki
, p. 3773 - 3782 (2007/10/02)
Synthesis of fixed-distance triads consisting of zinc porphyrin (ZnP), metal-free porphyrin (H2P), and pyromellitimide (PIm) or 1,4:5,8- naphthalenetetracarboximide (NIm) is described. The ZnP and H2P moietics are bridged by aromatic
