33733-78-7

Basic information

• Product Name: Benzene, 1-ethoxy-4-(methylthio)-
• CAS NO: 33733-78-7
• Molecular Formula: C9H12OS
• Molecular Weight: 168.26
• Mol File: 33733-78-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-ethoxy-4-(methylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-ethoxy-4-(methylthio)-(33733-78-7)
• EPA Substance Registry System: Benzene, 1-ethoxy-4-(methylthio)-(33733-78-7)

Safety Data

• Hazardous Substances Data: 33733-78-7(Hazardous Substances Data)

Upstream product

• 156-43-4 4-Ethoxyaniline 
• 13532-18-8 methyl 3-(methylthio)propionate 
• 699-08-1 1-ethoxy-4-iodobenzene 
• 34047-39-7 4-methylsulfanyl-2-butanone 
• 18542-42-2 (2-aminoethyl)methylsulfide 
• 2432-51-1 ethylthioacetic acid methyl ester 
• 5271-38-5 2-methylmercapto-ethanol 
• 106-46-7 para-dichlorobenzene 
• 4856-13-7 cuprous methylmercaptide 
• 123-09-1 4-chlorophenyl methyl sulfide 
• 141-52-6 sodium ethanolate 
• 699-09-2 4-ethoxy-benzenethiol 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 5286-01-1 1-ethoxy-4-thiocyanatobenzene 
• 40669-11-2 (+/-)-Methyl-<4-aethoxy-phenyl>-sulfoxid 
• 19760-88-4 4-Ethoxyphenyl methyl sulphone 

Relevant articles and documents

Palladium-catalyzed intermolecular transthioetherification of aryl halides with thioethers and thioesters

Functional group transfer reactions are an important synthetic tool in modern organic synthesis. Herein, we developed a new palladium-catalyzed intermolecular transthioetherification reaction of aryl halides with thioethers and thioesters. The synthetic utility and practicality of this catalytic protocol are demonstrated in a wide range of successful transformations (>70 examples). This catalytic protocol is applicable in carbonylative coupling processes as well, and the first example of carbonylative methylthioesterification of aryl halides has been achieved. Notably, this work also provides an approach to using natural products, such as methionine and selenomethionine, as the functional group sources.

A Simple Synthesis of Alkoxyaryl Alkyl Sulphides from Dichlorobenzene Derivatives

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