33734-07-5Relevant academic research and scientific papers
Formation of 1- and 2-Alkoxyenynes in Palladium-Catalyzed Cross-Coupling of 1- and 2-Bromoalkenyl Alkyl Ethers with Alkynes
Trostyanskaya,Shvetsov,Efimova,Kazankova,Beletskaya
, p. 946 - 950 (2007/10/03)
A preparative route to 1- and 2-alkoxyenynes is developed on the basis of stereoselective cross-coupling of 1- and 2-haloalkenyl alkyl ethers with terminal alkynes in the presence of palladium catalyst. Hydrolysis of 1- and 2-alkoxyenynes yields carbonyl derivatives containing a triple bond: substituted acetaldehyde and ketone, respectively.
