3380-46-9Relevant articles and documents
Metal-free oxidative aromatization of 2-aryloxycyclohex-2-en-1-ones to 2-aryloxyphenols using DDQ/Amberlyst-15
Jadhav,Samant
, p. 1301 - 1305 (2015/01/08)
Efficient metal-free oxidative aromatization of 2-aryloxycyclohex-2-en-1-ones was achieved by a combination of 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) and Amberlyst-15. The conditions for oxidative aromatization are mild and applicable for a variety of substrates, and Amberlyst-15 can be successfully recovered and recycled.
An umpoled synthon approach to the synthesis of 2-aryloxyphenols
Yeager,Schissel
, p. 28 - 30 (2007/10/02)
A convenient three-step method for the preparation of 2-aryloxyphenols from phenols and 2-fluorobenzaldehyde is described. Condensation of phenols with 2-fluorobenzaldehyde produces the intermediate 2-aryloxybenzaldehydes in 83-95% yield. These products rapidly undergo meta-chloroperbenzoic acid (m-CPBA) promoted Baeyer-Villiger oxidation to yield the corresponding 2-aryloxyphenyl formates which are hydrolyzed, without isolation, to give the desired 2-aryloxyphenols in 79-96% yield.
Studies on diphenyl ether derivatives. II. Synthesis and pharmacological actions of 2-dialkylaminoalkoxy-diphenyl ether derivatives. (2)
Toyoshima,Tanaka,Ogo,Hashimoto
, p. 1417 - 1425 (2007/10/05)
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