338460-84-7

Upstream product

• 338460-92-7 (1R,4S,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-1,6-bis-hydroxymethyl-cyclohex-2-enol 
• 338460-83-6 dimethyl (1S,2R,5S)-5-tert-butyldimethylsilyloxy-2-hydroxy-3-cyclohexene-1,2-dicarboxylate 
• 203627-51-4 (1S,2R,5S)-2,5-Dihydroxy-cyclohex-3-ene-1,2-dicarboxylic acid dimethyl ester 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 338460-85-8 (1S,4S,6R)-4-tert-butyldimethylsilyloxy-6-hydroxymethyl-2-cyclohexenol 
• 338460-86-9 (3S,4R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-4-trimethylsilanyloxymethyl-cyclohexene 
• 1151903-44-4 (1S,2R,3S,4R,5R)-2,3,4-tris(benzyloxy)-5-(benzyloxymethyl)-cyclohexanol 
• 1313195-33-3 (1S,4S,5R)-4-O-benzyl-5-benzyloxymethyl-1-O-(tert-butyldimethylsilyl)cyclohex-2-en-1,4-diol 
• 1313195-34-4 tert-butyldimethylsilyl 4,6-di-O-benzyl-5a-carba-α-D-mannopyranoside 
• 1313195-35-5 tert-butyldimethylsilyl 2,3,4,6-tetra-O-benzyl-5a-carba-α-D-mannopyranoside 
• 1313195-32-2 5a-carba-α-D-mannopyranose-6-phosphate 
• 135820-00-7 5a-carba-α-D-mannopyranose 
• 115184-64-0 (1S,2R,3S,4R,5R)-5-(acetoxymethyl)cyclohexane-1,2,3,4-tetrayl tetraacetate 

Relevant academic research and scientific papers

Asymmetric synthesis of (-)- and (+)-eutipoxide B using a base-catalyzed Diels-Alder reaction

The asymmetric synthesis of eutipoxide B, a metabolite of the phytopathogenic fungus Eutypa lata, is described. Quick and efficient synthesis of each enantiomer was achieved through base-catalyzed asymmetric Diels-Alder reactions with 3-hydroxy-2-pyrone and chiral acrylates.

A chemoenzymatic synthesis of 5a-carba-α-D-mannose-6-phosphate

An efficient chemical synthesis of 5a-carba-α-D-mannose and its enzymatic elaboration to 5a-carba-α-D-mannose-6-phosphate, using yeast hexokinase, is described.