33852-38-9Relevant academic research and scientific papers
Palladium-Catalyzed Alkene Carboamination Reactions of Electron-Poor Nitrogen Nucleophiles
Peterson, Luke J.,Wolfe, John P.
, p. 2339 - 2344 (2015/07/27)
Modified reaction conditions that facilitate Pd-catalyzed alkene carboamination reactions of electron-deficient nitrogen nucleophiles are reported. Pent-4-enylamine derivatives bearing N-tosyl or N-trifluoroacetyl groups are coupled with aryl triflates to
N-Heterocyclic carbene-gold(I)-catalyzed carboheterofunctionalization of alkenes with arylboronic acids
Zhu, Shifa,Ye, Lijuan,Wu, Wanqing,Jiang, Huanfeng
supporting information, p. 10375 - 10383 (2013/11/19)
A new approach to the synthesis of pyrrolidine, tetrahydrofuran, and imidazolidin-2-one via N-heterocyclic carbene-gold(I)-catalyzed intramolecular amino- or oxyarylation reactions from a wide variety of alkene substrates such as N-allyl amides, alcohols, carboxylic acids, and ureas in the presence of Selectfluor under mild conditions has been developed.
Gold-catalyzed intramolecular aminoarylation of alkenes: C-C bond formation through bimolecular reductive elimination
Brenzovich Jr., William E.,Benitez, Diego,Lackner, Aaron D.,Shunatona, Hunter P.,Tkatchouk, Ekaterina,Goddard III, William A.,Toste, F. Dean
supporting information; experimental part, p. 5519 - 5522 (2010/09/05)
(Chemical equation presented) Gold-ilocks and the 3 mol% catalyst: Bimetallic gold bromides allow the room temperature aminoarylation of unactivated terminal olefins with aryl boronic acids using Selectfluor as an oxidant. A catalytic cycle involving gold (I)/gold(III) and a bimolecular reductive elimination for the key C-C bond-forming step is proposed, dppm= bis(diphenylphosphanyl) methane.
