33901-10-9Relevant academic research and scientific papers
Cyano-borrowing: Titanium-catalyzed direct amination of cyanohydrins with amines and enantioselective examples
Li, Qian,Li, Qing-Hua,Li, Wan-Fang,Li, Zhao-Feng,Liu, Tang-Lin,Peng, Yun-Gui,Ren, Li-Qing,Tao, Jing
supporting information, p. 651 - 654 (2020/01/28)
The direct amination of cyanohydrins with amines via a catalytic cyano-borrowing reaction was developed. The transformation features broad substrate scope, excellent functional group compatibility, and very mild and simple operations. Moreover, a titanium
An in-based 3D metal-organic framework as heterogeneous Lewis acid catalyst for multi-component Strecker reactions
Chai, Juan,Zhang, Ping,Xu, Jianing,Qi, Hui,Sun, Jing,Jing, Shubo,Chen, Xiaodong,Fan, Yong,Wang, Li
, p. 165 - 171 (2018/05/07)
A novel three-dimensional metal-organic framework (MOF) {[In3(NIPH)3 (HNIPH)(OH)2]·4H2O}n (1) (H2NIPH = 5-nitroisophthalic acid) with one-dimensional channels was synthesized and structurally characterized. Importantly, it demonstrates excellent catalytic activity for the Strecker reactions of two or three components under mild conditions. Moreover, the catalytic recycling of 1 as a representative example was explored. It can be easily separated and reused for no less than five runs with more than 80% conversion yield in catalytic ability.
In situ generation of functionality in a reactive binicotinic-acid-based ligand for the design of multi-functional copper(ii) complexes: Syntheses, structures and properties
Deng, Dongsheng,Guo, Hui,Kang, Guohui,Ma, Lufang,He, Xu,Ji, Baoming
, p. 1871 - 1880 (2015/03/04)
Under hydrothermal conditions, including tuning the reaction ratio and reaction temperature, three-dimensional (3D) porous {[Cu3(hbpdc)(OH)2(H2O)]·2H2O} (1), two-dimensional (2D) sheet {Cu2(hbpdc)(Hs
Vanadium-catalyzed oxidative Strecker reaction: α-C-H cyanation of para-methoxyphenyl (PMP)-protected primary amines
Chen, Chuo,Zhu, Chen,Xia, Ji-Bao
supporting information, p. 232 - 234 (2014/01/06)
We describe an oxidative Strecker reaction that allows for direct cyanation of para-methoxyphenyl (PMP)-protected primary amines. A vanadium(V) complex was used as the catalyst and TBHP as the oxidant. The cyanation occurs at the α-C position bearing either an alkyl or an aromatic group. This method provides a direct access to α-aminonitrile from amines with one-carbon extension.
