33915-37-6Relevant academic research and scientific papers
Transition metal complexes incorporating the BF2 ligand formed by oxidative addition of the B-B bond in B2F4
Lu, Norman,Norman, Nicholas C.,Guy Orpen,Quayle, Michael J.,Timms, Peter L.,Whittell, George R.
, p. 4032 - 4037 (2007/10/03)
The reactions between B2F4 and the platinum and iridium complexes [Pt(PPh3)2(η-C2H4)], [Pt(dppb)(r)-C2H4)] [dppb = l,4-bis(diphenylphosphino)butane] and trans-[IrCl(CO)(PPh3)2] afforded the difluoroboryl complexes cis-[Pt(BF2)2(PPh3)2], cis-[Pt(BF2)2(dppb)] and fac-[Ir(BF2)3(CO)(PPh3)2] respectively all of which have been characterised by X-ray crystallography. The isoelectronic platinum dppb nitrito complex cw-[Pt(NO2)2(dppb)] has also been prepared and structurally characterised. The Royal Society of Chemistry 2000.
Electrophilic cleavage of C-F bonds in hydrido trifluoromethyl complexes of platinum(II) by proton acids. Synthesis of hydrido carbene and hydrido carbonyl derivatives and X-ray structures of trans-PtH(CF3)(PPh3)2 (180 K)
Michelin, Rino A.,Ros, Renzo,Guadalupi, Giuseppe,Bombieri, Gabriella,Benetollo, Franco,Chapuis, Gervais
, p. 840 - 846 (2008/10/08)
The low-temperature (180 K) crystal and molecular structure of the hydridoplatinum(II) complex trans-PtH(CF3)(PPh3)2 (1) has been determined by X-ray diffraction. The monoclinic crystal, space group P21/n, has l
