339175-67-6Relevant academic research and scientific papers
Synthesis of Aryl Alkynes via Copper Catalyzed Decarboxylative Alkynylation of 2-Nitrobenzoic Acids
Yu, Yongqi,Chen, Xiang,Wu, Qianlong,Liu, Da,Hu, Liang,Yu, Lin,Tan, Ze,Gui, Qingwen,Zhu, Gangguo
supporting information, p. 8556 - 8566 (2018/06/29)
An efficient protocol for the synthesis of internal aryl alkynes was achieved via Cu-catalyzed decarboxylative cross-coupling reactions, and to the best of our knowledge, this is the first example of a Cu-catalyzed decarboxylative alkynylation of benzoic acids with terminal alkynes. This approach utilizes simple Cu salt as catalyst and O2, an abundant, clean, and green material, as the oxidant. The reaction tolerates various functional groups, and a variety of internal aryl alkynes were synthesized in 46-83% yields.
Phenylene ethynylene diazonium salts as potential self-assembling molecular devices
Kosynkin, Dmitry V.,Tour, James M.
, p. 993 - 995 (2007/10/03)
(matrix presented) Functionalized diazonium salts for molecular electronic devices are prepared by the reaction of the corresponding anilines with NOBF4 in sulfolane-acetonitrile solvent.
Synthesis of potential molecular electronic devices containing pyridine units
Chanteau, Stephanie H.,Tour, James M.
, p. 3057 - 3060 (2007/10/03)
Conjugated linear molecules containing pyridyl groups as 'alligator clips' have been synthesized as potential molecular electronic devices using palladium-catalyzed couplings.
Accoutrements of a molecular computer: Switches, memory components and alligator clips
Dirk, Shawn M.,Price Jr., David W.,Chanteau, Stephanie,Kosynkin, Dmitry V.,Tour, James M.
, p. 5109 - 5121 (2007/10/03)
Several second generation memory components consisting of oligo(phenylene ethynylene)s containing easily reducible functionalities consisting of either nitro or quinone cores have been synthesized for incorporation into molecular electronic devices. Addit
