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3315-32-0

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3315-32-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 3315-32-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,3,1 and 5 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 3315-32:
(6*3)+(5*3)+(4*1)+(3*5)+(2*3)+(1*2)=60
60 % 10 = 0
So 3315-32-0 is a valid CAS Registry Number.

3315-32-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,4,6-tri-tert-butyl-phenoxide radical

1.2 Other means of identification

Product number -
Other names 2,4,6-tri(tert-butyl)phenoxyl radical

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3315-32-0 SDS

3315-32-0Relevant articles and documents

One to Find Them All: A General Route to Ni(I)-Phenolate Species

Bismuto, Alessandro,Finkelstein, Patrick,Jeschke, Gunnar,Müller, Patrick,Morandi, Bill,Trapp, Nils

supporting information, p. 10642 - 10648 (2021/07/31)

The past 20 years have seen an extensive implementation of nickel in homogeneous catalysis through the development of unique reactivity not easily achievable by using noble transition metals. Many catalytic cycles propose Ni(I) complexes as potential reac

A Reactive, Photogenerated High-Spin (S = 2) FeIV(O) Complex via O2Activation

Albert, Therese,Bill, Eckhard,Dey, Aniruddha,Goldberg, David P.,Gordon, Jesse B.,Mo?nne-Loccoz, Pierre,Sabuncu, Sinan,Siegler, Maxime A.

, p. 21637 - 21647 (2022/01/03)

Addition of dioxygen at low temperature to the non-heme ferrous complex FeII(Me3TACN)((OSiPh2)2O) (1) in 2-MeTHF produces a peroxo-bridged diferric complex Fe2III(μ-O2)(Me3TACN)2((OSiPh2)2O)2 (2), which was characterized by UV-vis, resonance Raman, and va

Concerted proton-electron transfer oxidation of phenols and hydrocarbons by a high-valent nickel complex

Fisher, Katherine J.,Feuer, Margalit L.,Lant, Hannah M. C.,Mercado, Brandon Q.,Crabtree, Robert H.,Brudvig, Gary W.

, p. 1683 - 1690 (2020/02/25)

The high-valent nickel(iii) complex Ni(pyalk)2+ (2) was prepared by oxidation of a nickel(ii) complex, Ni(pyalk)2 (1) (pyalk = 2-pyridyl-2-propanoate). 2 and derivatives were fully characterized by mass spectrometry and X-ray crystallography. Electron paramagnetic resonance spectroscopy and X-ray photoelectron spectroscopy confirm that the oxidation is metal-centered. 2 was found to react with a variety of phenolic and hydrocarbon substrates. A linear correlation between the measured rate constant and the substrate bond dissociation enthalpy (BDE) was found for both phenolic and hydrocarbon substrates. Large H/D kinetic isotope effects were also observed for both sets of substrates. These results suggest that 2 reacts through concerted proton-electron transfer (CPET). Analysis of measured thermodynamic parameters allows us to calculate a bond dissociation free energy (BDFE) of ~91 kcal mol-1 for the O-H bond of the bound pyalk ligand. These findings may shed light onto CPET steps in oxidative catalysis and have implications for ligand design in catalytic systems.

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