3392-93-6

Upstream product

• 1774-50-1 10-(4-nitro-benzenesulfonyloxy)-deca-1,5t-diene 
• 5162-44-7 1-bromo-4-butene 
• 286-20-4 cyclohexane-1,2-epoxide 
• 705-86-2 (+/-)-δ-decanolactone 
• 16178-83-9 2-(3-butenyl)cyclohexanone 
• 174707-96-1 (E)-9-Deca-5,9-dien-1-ol 
• 90925-12-5 deca-5,9-diyn-1-ol 
• 7103-09-5 4-but-1-enylmagnesium bromide 

Downstream Products

• 101859-52-3 C₂₃H₂₆Cl₂O 
• 101976-90-3 2,4-Dichloro-benzoic acid (2S,3R,5aS,9aR)-3-formyloxy-decahydro-benzo[b]oxepin-2-ylmethyl ester 
• 101859-02-3 (1R*,3R*,6S*)-3-<(1S*)-2-((2,4-dichlorobenzoyl)oxy)-1-iodoethyl>-2-oxabicyclo<4.4.0>decane 
• 101858-99-5 (1R*,3R*,6S*)-3-((1R*)-2-((2,4-dichlorobenzoyl)oxy)-1-iodoethyl)-2-oxabicyclo<4.4.0>decane 
• 101859-03-4 (1R*,3S*,6S*)-3-((1S*)-2-((2,4-dichlorobenzoyl)oxy)-1-iodoethyl)-2-oxabicyclo<4.4.0>decane 
• 101859-37-4 (E)-5-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-pent-2-enoic acid methyl ester 
• 101859-37-4 (Z)-5-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-pent-2-enoic acid methyl ester 
• 101859-39-6 (E)-5-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-pent-2-en-1-ol 
• 101859-39-6 (Z)-5-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-pent-2-en-1-ol 
• 101859-56-7 2,4-Dichloro-benzoic acid (E)-5-{(1S,2R)-2-[bis-(4-chloro-phenyl)-methoxy]-cyclohexyl}-pent-2-enyl ester 
• 101859-54-5 (E)-5-{(1S,2R)-2-[Bis-(4-chloro-phenyl)-methoxy]-cyclohexyl}-pent-2-enoic acid methyl ester 
• 101859-01-2 2,4-Dichloro-benzoic acid (E)-5-[(1S,2R)-2-(4-bromo-benzyloxy)-cyclohexyl]-pent-2-enyl ester 
• 101859-38-5 2,4-Dichloro-benzoic acid (Z)-5-[(1S,2R)-2-(tert-butyl-dimethyl-silanyloxy)-cyclohexyl]-pent-2-enyl ester 
• 101859-55-6 (E)-5-{(1S,2R)-2-[Bis-(4-chloro-phenyl)-methoxy]-cyclohexyl}-pent-2-en-1-ol 

Relevant academic research and scientific papers

Dynamic ligand exchange in reactions of samarium diiodide

Mechanistic studies show the importance of iodide displacement by additives that accelerate reactions of samarium diiodide. The key feature important for acceleration of reaction rate is the use of proton donors and other additives that have a high enough affinity for Sm(II) to displace iodide yet do not saturate the coordination sphere inhibiting substrate reduction.

Dibromomethane as one-carbon source in organic synthesis: A versatile methodology to prepare the cyclic and acyclic α-methylene or α-keto acid derivatives from the corresponding terminal alkenes

Ozonolysis of mono-substituted alkenes A-1 followed by reacting with a preheated mixture of CH2Br2-Et2NH affords α-substituted acroleins A-2 in good yields. Under very mild reaction conditions, these α-substituted acroleins A-2 can be easily converted to α-methylene esters A-4, which could be further converted to the corresponding α-keto esters A-5. This methodology can be also applied to the preparation of α-methylene lactones B-4, α-methylene lactams, and α-keto lactones B-5 with various ring sizes.