339267-93-5Relevant academic research and scientific papers
Homogeneous Dimerization Catalysts Based on Vanadium
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Page/Page column 5, (2011/04/18)
A series of new bis(imino)pyridine vanadium(III) complexes was synthesized according to formula: They were tested for the homogeneous catalytic dimerization of propylene after activation with MAO and showed excellent selectivity for dimerization. The catalysts can be used with or without PPh3 as an additive to produce ≧80% dimerized alkenes.
Homogeneous catalytic dimerization of propylene with bis(imino)pyridine vanadium(III) complexes
Lang, Julian R.V.,Denner, Christine E.,Alt, Helmut G.
experimental part, p. 45 - 49 (2010/07/08)
A series of new bis(imino)pyridine vanadium(III) complexes was synthesized. They were tested for the homogeneous catalytic dimerization of propylene after activation with MAO. The activity and selectivity depend on the ligand structure of the corresponding organic coordination compound. The influence of PPh3 as an additive was investigated and high dependency could be observed.
