3400-36-0Relevant academic research and scientific papers
Dealkoxylation ofN-alkoxyamides without an external reductant driven by Pd/Al cooperative catalysis
Suzuki, Hirotsugu,Shiomi, Takahiro,Yoneoka, Kenji,Matsuda, Takanori
supporting information, p. 7545 - 7548 (2020/10/15)
Lewis acid-assisted palladium-catalysed dealkoxylation ofN-alkoxyamides has been developed. This reaction proceeded smoothly with a range ofN-alkoxyamides in the absence of an external reductant, thereby establishing a convenient and reductant-free protocol. In addition, a gram-scale reaction could be achieved. Preliminary mechanistic investigations indicated that β-hydrogen elimination from a palladium alkoxide intermediate generated an intramolecular hydride source.
The influence of reaction conditions on the Diels-Alder cycloadditions of 2-thio-3-chloroacrylamides; Investigation of thermal, catalytic and microwave conditions
Kissane, Marie,Lynch, Denis,Chopra, Jay,Lawrence, Simon E.,Maguire, Anita R.
supporting information; experimental part, p. 5602 - 5613 (2011/02/18)
The Diels-Alder cycloadditions of cyclopentadiene and 2,3-dimethyl-1,3- butadiene to a range of 2-thio-3-chloroacrylamides under thermal, catalytic and microwave conditions is described. The influence of reaction conditions on the outcome of the cycloaddi
N-methylation of substituted benzonitriles with methyl fluorosulfonate
Salfetnikova,Vasil'ev,Rudenko
, p. 838 - 844 (2007/10/03)
Substituted benzonitriles ArCN treated at 20-70°C with methyl fluorosulfonate yield the corresponding N-methylbenzamides ArCONHMe. Compounds with two cyano groups afford N,N′-methylated diamides.
(Phenylalkylaminoalkyloxy)-heteroaryl-compounds, processes and intermediates for their production and pharmaceutical compositions containing them
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, (2008/06/13)
3-(Phenylalkylaminoalkylozy)-heteroaryl compounds having heart rate lowering and/or anti-ischemic effects, methods for their preparation and pharmaceutical compositions containing them are described. The compounds correspond to the general formula I STR1 or to the general formula XXXI STR2 in which the substituents have the meanings given the specification.
