34010-82-7

Upstream product

• 603-35-0 triphenylphosphine 

Downstream Products

• 107769-45-9 [(PPh3)2Cu(μ-3,6-bis(2-pyridyl)-1,2,4,5-tetrazine)(Cu(PPh3)2)](2+) 
• 227297-77-0 [(η(2)-1-methyl-2-((methylthio)methyl)-1H-benzimidazole)Cu(PPh3)2]BF4 
• 265125-52-8 [C₅H₄NC(O)Fe(C₅H₅)(CO)2]Cu(P(C₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=C₅H₄NC(O)Fe(C₅H₅)(CO)2Cu(P(C₆H₅)3)2BF₄ 
• 1372802-36-2 [Cu((4-iPrC₆H₄)2acenaphthenequinonediimine)(PPh₃)2]BF₄ 
• 1446405-12-4 [Cu((4-MeOC₆H₄)2acenaphthenequinonediimine)(PPh₃)2]BF₄ 
• 1446405-14-6 [Cu((4-NO₂C₆H₄)2acenaphthenequinonediimine)(PPh₃)2]BF₄ 
• 1446405-16-8 [Cu((2-iPrC₆H₄)2acenaphthenequinonediimine)(PPh₃)2]BF₄ 
• 1415558-79-0 C₆₄H₄₆CuN₂P₂⁽¹⁺⁾*BF₄^(1-) 
• 80320-16-7 (2,2'-bipyridyl)bis(triphenylphosphine)copper(I) tetrafluoroborate 
• 124021-09-6 1,3-dimethyllumazine bis(triphenylphosphine)copper(I) tetrafluoroborate 

Relevant academic research and scientific papers

Thermal decomposition and stability in a series of tetrafluorborate copper(I) complexes

Tetrafluorborate copper(I) complexes containing acetonitrile, triphenylphosphine, 1,10-phenanthroline,2,2'-bipyridine and 2-quinolinethiol have been prepared in order to study their thermal stabilities as a function of the ligands present. The characterization of the above compound was carried out by elemental analysis and IR spectroscopy. Their thermal behaviour has been investigated and the final products were identified by X-ray powder diagrams.

Synthesis and Solution Multinuclear Magnetic Resonance Studies of Homoleptic Copper(I) Complexes of Group 15 Donor Ligands

The homoleptic complexes Y (L = PMe3, PMe2Ph, PMePh2, PPh3, PPh2H, PPhH2, AsMe3, AsMe2Ph, AsMePh2, AsPh3, SbMe3, SbEt3 or SbPh3; Y = PF6 or BF4) and Y have been prepared from Y and L or L-L.The 63Cu and, where appropriate 31P- NMR spectra, have been recorded from CH2Cl2 solutions of the complexes over the temperature range 300-175 K, including the first reported 63Cu resonances from arsenic and antimony donor ligand compounds.The effects of ligand size and geometry upon the 63Cu NMR spectra are discussed and typical copper chemical-shift ranges for Group 15 donor ligand compounds established.The structure of PF6 has been established by X-ray crystallography: orthorhombic, space group P212121, a = 14.775(6), b = 16.991(5), c = 21.027(6) Angstroem, Z = 4.The copper atom is in a distorted tetrahedral environment .