340146-58-9

Basic information

• Product Name: (2S,4S)-3-Benzyl-4-isopropyl-2-methyl-[1,3,2]oxazaphospholidine 2-oxide
• Synonyms: (2S,4S)-3-Benzyl-4-isopropyl-2-methyl-[1,3,2]oxazaphospholidine 2-oxide
• CAS NO: 340146-58-9
• Molecular Weight: 253.281
• Mol File: 340146-58-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,4S)-3-Benzyl-4-isopropyl-2-methyl-[1,3,2]oxazaphospholidine 2-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,4S)-3-Benzyl-4-isopropyl-2-methyl-[1,3,2]oxazaphospholidine 2-oxide(340146-58-9)
• EPA Substance Registry System: (2S,4S)-3-Benzyl-4-isopropyl-2-methyl-[1,3,2]oxazaphospholidine 2-oxide(340146-58-9)

Safety Data

• Hazardous Substances Data: 340146-58-9(Hazardous Substances Data)

Upstream product

• 676-97-1 methylphosphonic acid dichloroanhydride 
• 42807-42-1 N-benzyl-L-valinol 

Downstream Products

• 340146-59-0 1-((2S,4S)-3-Benzyl-4-isopropyl-2-oxo-2λ⁵-[1,3,2]oxazaphospholidin-2-yl)-propan-2-one 
• 340146-60-3 3-((2S,4S)-3-Benzyl-4-isopropyl-2-oxo-2λ⁵-[1,3,2]oxazaphospholidin-2-yl)-6,7-dimethoxy-2-methyl-quinoline 

Relevant articles and documents

New NADH models bearing a phosphonate or a chiral oxazaphospholidine oxide at the dihydropyridine ring

Novel NADH models bearing a phosphonate at the 3-position of a stable 1,4-dihydroquinoline structure were successfully involved in the reduction of methyl benzoylformate. Asymmetric reduction of the former ketone with a NADH model bearing a chiral oxazaphospholidine oxide is reported affording methyl benzoylformate in 45% e.e.