34021-58-4Relevant academic research and scientific papers
Rhodium-catalyzed Beckmann rearrangement
Arisawa, Mieko,Yamaguchi, Masahiko
, p. 311 - 312 (2001)
equation presented Beckmann rearrangement of oxime is catalyzed by [RhCl(cod)]2, trifluoromethanesulfonic acid, and tris(p-tolyl)phosphine in refluxing dichloroethane, giving the corresponding amide in good yield. Product/acid ratios of 10:20 can be attained in the reaction of benzophenone oximes.
