340254-93-5Relevant academic research and scientific papers
Reactivity of 1-hydro-5-carbaphosphatrane based on tautomerization between pentavalent phosphorane and trivalent cyclic phosphonite
Kobayashi, Junji,Goto, Kei,Kawashima, Takayuki,Schmidt, Michael W.,Nagase, Shigeru
, p. 3811 - 3820 (2006)
The reaction behavior of 1-hydro-5-carbaphosphatrane (1a) was examined. Treatment of 1a with oxidants such as 3-chloroperoxybenzoic acid (mCPBA) and tBuOCl gave cyclic phosphonate 2 and 1-chloro-5-carbaphosphatrane (4), respectively, via cyclic phosphonit
Synthesis, structure, and bonding properties of 5-carbaphosphatranes: A new class of main group atrane
Kobayashi, Junji,Goto, Kei,Kawashima, Takayuki,Schmidt, Michael W.,Nagase, Shigeru
, p. 3703 - 3712 (2007/10/03)
1-Hydro-5-carbaphosphatrane (1) and 1-methyl-5-carbaphosphatrane (2), the first 5-carbon analogues of phosphatranes, were synthesized by a demethylation reaction of cyclic phosphinate 3. X-ray analysis revealed that 1 has a typical trigonal bipyramidal st
