340270-37-3

Basic information

• Product Name: [Os(C₂CH₃)(H)(CS)(CO)(P(C₆H₅)3)2]
• CAS NO: 340270-37-3
• Molecular Weight: 826.934
• Mol File: 340270-37-3.mol

Chemical Properties

• CAS DataBase Reference: [Os(C₂CH₃)(H)(CS)(CO)(P(C₆H₅)3)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Os(C₂CH₃)(H)(CS)(CO)(P(C₆H₅)3)2](340270-37-3)
• EPA Substance Registry System: [Os(C₂CH₃)(H)(CS)(CO)(P(C₆H₅)3)2](340270-37-3)

Safety Data

• Hazardous Substances Data: 340270-37-3(Hazardous Substances Data)

Upstream product

• 75-09-2 dichloromethane 
• 64883-46-1 [Os(CS)(CO)(P(C₆H₅)3)3] 
• 74-99-7 prop-1-yne 

Relevant articles and documents

Reaction between the thiocarbonyl complex, Os(CS)(CO)(PPh3)3, and propyne: Crystal structure of a new sulfur-substituted osmabenzene

Reaction between Os(CS)(CO)(PPh3)3 and propyne gives a complex mixture of products from which can be isolated the simple oxidative addition product Os(C?CMe)H(CS)(CO)(PPh3)2 (1) and the osmabenzene Os(η2-C[S]CMeCHCHCMe)(CO)(PPh3)2 (2), where the two propyne molecules in the osmabenzene ring have linked tail-to-tail. Treatment of 1 with HCl gives, as the ultimate product, the propenylthioacyl complex, Os(η2-C[S]CH=CHMe)Cl(CO)(PPh3)2 (3). The crystal structures of compounds 1-3 have been determined.