34029-54-4

Upstream product

• 2443-46-1 1,6-methano[10]annulene 
• 102836-13-5 Trimethyl-(7-methyl-bicyclo[4.4.1]undeca-1,3,5,7,9-pentaen-2-yl)-silane 
• 40563-42-6 1,6-Methano-<10>annulen-2-carbaldehyd 
• 15825-92-0 2-bromo-1,6-methano[10]annulene 
• 74-88-4 methyl iodide 

Relevant academic research and scientific papers

Electrophilic Substitution in Annulenes. Part 4. Transmission of Substituent Effects in 1,6-Methanoannulene, determined via Protiodesilylation: Evidence for Substantial C(1)-C(6) Transannular Orbital Interaction

The rates of acid-catalysed desilylation of a series of 7-substituted 2-trimethylsilyl-1,6-methanoannulenes have been measured spectrophotometrically at 50 degC using a mixture of aqueous perchloric acid and methanol (2:5 v/v).The substituent effects

Applications of MCD Spectroscopy: MO Ordering and Transannular Interaction in 1,6-Methanoannulenes from Analysis of Substituent Effects

Eight 2-substituted and nine 3-substituted 1,6-methanoannulenes have been synthesized, and their magnetic circular dichroism has been measured.The B terms of the Lb transition depend on the ?-electron effect of the substituent in a way which reveals the ordering of the four frontier molecular orbitals: a1, a2, b1, and b2 in the order of increasing energy.This result implies the presence of a strong transannular interaction between the bridgehead positions 1 and 6 on the bridged annulene ring.