Electrophilic Substitution in Annulenes. Part 4. Transmission of Substituent Effects in 1,6-Methanoannulene, determined via Protiodesilylation: Evidence for Substantial C(1)-C(6) Transannular Orbital Interaction

DOI: 10.1039/P29880000697

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 697 - 700 (1988)

Update date:2022-07-30

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Authors:

Suzuki, Tsuyoshi

Takase, Kahei

Takahashi, Kazuko

Laws, Andrew P.

Taylor, Roger

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Article abstract of DOI:10.1039/P29880000697

The rates of acid-catalysed desilylation of a series of 7-substituted 2-trimethylsilyl-1,6-methano<10>annulenes have been measured spectrophotometrically at 50 degC using a mixture of aqueous perchloric acid and methanol (2:5 v/v).The substituent effects

Full text of DOI:10.1039/P29880000697

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