34074-16-3Relevant academic research and scientific papers
CATIONIC SILICON (II) COMPOUNDS AND METHOD FOR THE PRODUCTION THEREOF
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Paragraph 0056, (2019/06/07)
The invention relates to a method for producing cationic silicon(II) compounds of general formula I [in-line-formulae](RaSi)+HA???(I)[/in-line-formulae]by reacting the silicon(II) compounds of general formula II [in-line-formulae](Rb-H)(RaSi)+??(II)[/in-line-formulae]with a hydride acceptor compound A,wherein Ra, (Rb-H) and A have the definitions described in claim 1; to the cationic silicon(II) compounds of general formula I and use thereof as catalysts.
Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes
Noda, Daisuke,Tahara, Atsushi,Sunada, Yusuke,Nagashima, Hideo
supporting information, p. 2480 - 2483 (2016/03/12)
A mixture of an iron or a cobalt carboxylate and an isocyanide ligand catalyzed the hydrosilylation of alkenes with hydrosiloxanes with high efficiency (TON >103) and high selectivity. The Fe catalyst showed excellent activity for hydrosilylation of styrene derivatives, whereas the Co catalyst was widely effective in reaction of alkenes. Both of them catalyzed the reaction with allylic ethers. Chemical modification and cross-linking of silicones were achieved by choosing the right catalyst and reaction conditions.
