34074-21-0Relevant academic research and scientific papers
Hydrosilylation of 2-Phenylpropene with dichloromethylsilane and transformations of the resulting adduct
Yarosh
, p. 1555 - 1556 (2007/10/03)
2-Phenylpropene was hydrosilylated with dichloromethylsilane in the presence of H2PtCl6 to synthesize dichloromethyl(2-phenylpropyl)silane. The latter was reacted with methanol in the presence of carbamide to obtain dimethoxymethyl(2-phenylpropyl)silane, whose reaction with methylmagnesium iodide gave methoxydimethyl(2-phenylpropyl)silane. Treatment of the latter with 40% HF gave fluorodimethyl(2-phenylpropyl)silane which was reacted with BrMgC≡CH to obtain dimethylethynyl(2-phenylpropyl)silane.
