13617-28-2Relevant articles and documents
Hydrosilylation of 2-Phenylpropene with dichloromethylsilane and transformations of the resulting adduct
Yarosh
, p. 1555 - 1556 (2007/10/03)
2-Phenylpropene was hydrosilylated with dichloromethylsilane in the presence of H2PtCl6 to synthesize dichloromethyl(2-phenylpropyl)silane. The latter was reacted with methanol in the presence of carbamide to obtain dimethoxymethyl(2-phenylpropyl)silane, whose reaction with methylmagnesium iodide gave methoxydimethyl(2-phenylpropyl)silane. Treatment of the latter with 40% HF gave fluorodimethyl(2-phenylpropyl)silane which was reacted with BrMgC≡CH to obtain dimethylethynyl(2-phenylpropyl)silane.
Process for the preparation of organosilicon compounds
-
, (2008/06/13)
This invention relates to the preparation of organosilicon compounds by the addition of a silicon compound containing Si-bonded hydrogen to a compound having an aliphatic multiple bond in the presence of a catalyst which promotes the addition of Si-bonded hydrogen to compounds containing an aliphatic multiple bond. In this process the reactants and the catalyst are continuously introduced into a pipe-shaped reactor while the contents of the reactor, which are maintained in a liquid phase by the application of pressure are circulated in the reactor at a rate of at least 1,000 cm per minute and while the reaction mixture is continuously being removed from the reactor.