13617-28-2

Usage

Uses

Used in Material Sciences:
(3-Phenylpropyl)Methyldichlorosilane is used as an intermediate reagent for the synthesis of advanced materials, contributing to the development of new compounds with potential applications in various industries.
Used in Chemical Synthesis:
(3-Phenylpropyl)Methyldichlorosilane is used as a versatile reagent in chemical synthesis, allowing for the creation of a wide range of complex organic molecules, which can be further utilized in different fields such as pharmaceuticals, polymers, and specialty chemicals.
Used in Research and Development:
(3-Phenylpropyl)Methyldichlorosilane is used as a research compound in academic and industrial laboratories, where it is employed to explore new reaction pathways and develop innovative synthetic methods, further expanding the scope of its applications.

InChI:InChI=1/C10H14Cl2Si/c1-9(8-13(2,11)12)10-6-4-3-5-7-10/h3-7,9H,8H2,1-2H3

Upstream product

• 7787-92-0 dichloro-(2-chloro-propyl)-methyl-silane 
• 71-43-2 benzene 
• 7787-93-1 dichloro(3-chloropropyl)methylsilane 
• 75-54-7 Dichloromethylsilane 
• 98-83-9 isopropenylbenzene 

Downstream Products

• 18758-65-1 2,4,6-trimethyl-2,4,6-tris-(2-phenyl-propyl)-cyclotrisiloxane 
• 18027-28-6 trimethyl(2-phenylpropyl)silane 
• 28455-47-2 2,4,6-Trimethyl-2,4,6-tris-(2-phenyl-propyl)-[1,3,5,2,4,6]triazatrisilinane 
• 27329-85-7 2,4,6-Trimethyl-2,4,6-tris-(2-phenyl-propyl)-[1,3,5,2,4,6]trithiatrisilinane 
• 347194-22-3 dimethoxymethyl(2-phenylpropyl)silane 
• 34074-21-0 methoxydimethyl(2-phenylpropyl)silane 
• 347194-23-4 fluorodimethyl(2-phenylpropyl)silane 

Relevant academic research and scientific papers

Effect of the substituents at the silicon of (ω-chloroalkyl)silanes on the alkylation to benzene

(ω-Chloroalkyl)silanes [Cl3-mMemSi(CH2)n-Cl: m=0-3, n=1-3] underwent Friedel-Crafts alkylation with benzene in the presence of aluminum chloride to give alkylated products. Such alkylation reactions took place at temperatures ranging from room temperature (m=0-1, n=2, 3; m=3, n=1) to 80 (m=1, 2; n=1) and 200°C (m=0; n=1), depending on the substituent(s) of the silicon and the alkylene-chain spacer between the silicon and C-Cl bond of (ω-chloroalkyl)silanes. In the alkylation to benzene, the reactivities of (ω-chloroalkyl)silanes increase as the number (m) of methyl-group(s) at the silicon and the alkylene length between the silicon and C-Cl bond increases. While decomposition of alkylation products was observed at two more methyl groups substituted at silicon in the cases of (chloromethyl)silanes such as (chloromethyl)dimethylchlorosilane and (chloromethyl)trimethylsilane. The reaction with (chloromethyl)trimethylsilane occurred at room temperature to give trimethylchlorosilane, toluene and xylene via a decomposition reaction of the products. No (trimethylsilylmethyl)benzene was formed. In the alkylation to benzene, the reactivity of (ω-chloroalkyl)silanes decreases in the following order: m=3>2>1>0; n=3>2?1. The results are consistent with the stability of the carbocation generated by the complexation of (ω-chloroalkyl)silanes with aluminum chloride.

Hydrosilylation of 2-Phenylpropene with dichloromethylsilane and transformations of the resulting adduct

2-Phenylpropene was hydrosilylated with dichloromethylsilane in the presence of H2PtCl6 to synthesize dichloromethyl(2-phenylpropyl)silane. The latter was reacted with methanol in the presence of carbamide to obtain dimethoxymethyl(2-phenylpropyl)silane, whose reaction with methylmagnesium iodide gave methoxydimethyl(2-phenylpropyl)silane. Treatment of the latter with 40% HF gave fluorodimethyl(2-phenylpropyl)silane which was reacted with BrMgC≡CH to obtain dimethylethynyl(2-phenylpropyl)silane.

Process for the preparation of organosilicon compounds

This invention relates to the preparation of organosilicon compounds by the addition of a silicon compound containing Si-bonded hydrogen to a compound having an aliphatic multiple bond in the presence of a catalyst which promotes the addition of Si-bonded hydrogen to compounds containing an aliphatic multiple bond. In this process the reactants and the catalyst are continuously introduced into a pipe-shaped reactor while the contents of the reactor, which are maintained in a liquid phase by the application of pressure are circulated in the reactor at a rate of at least 1,000 cm per minute and while the reaction mixture is continuously being removed from the reactor.