34111-96-1

Upstream product

• 873-55-2 sodium benzenesulfonate 
• 619-23-8 3-Nitrobenzyl chloride 
• 80239-81-2 3-nitrobenzyl phenyl sulfide 

Downstream Products

• 135294-61-0 3-benzenesulfonylmethyl-aniline 
• 129527-21-5 1-(Benzenesulfonyl-methylsulfanyl-methyl)-3-nitro-benzene 
• 1403988-66-8 4-chloro-N-{3-[(phenylsulfonyl)methyl]phenyl}-1,3,5-triazin-2-amine 

Relevant academic research and scientific papers

SUBSTITUTED 4-ARYL-N-PHENYL-1,3,5-TRIAZIN-2-AMINES

The present invention relates to substituted 4-Aryl-N-phenyl-1,3,5-triazin-2-amines of general formula (I) as described and defined herein, and methods for their preparation, their use for the treatment and/or prophylaxis of disorders, in particular of hy

α-(METHYLTHIO)BENZYL SULFONES AS SYNTHETIC INTERMEDIATES. PART IV. SOME NEW o-,m- AND p-SUBSTITUTED α-(METHYLTHIO)- AND α,α'-BIS-(METHYLTHIO)-BENZYL SULFONES

The reaction of the meta nitro, methoxy and cyano substituted benzylic sulfones with an excess of dimethyl disulfide in the presence of NaH/DMSO, affords the corresponding α-monosulfenylated derivatives.However, no reaction occurs with the corresponding o-substituted sulfones.A new procedure is developed using S-methyl methanethiosulfonate, in excess, in the "phase transfer condition" which lead for the o-nitro and o-methoxy substituted sulfones to the α-monosulfenylated derivatives and for the o-cyano as well as p- and m-nitro, m-methoxy and m-cyano substituted benzylic sulfones to the correponding α,α'-bis-sulfenylated derivatives.