34182-03-1

Basic information

• Product Name: 2-Cyclohexen-1-one, 5-(1-hydroxy-1-methylethyl)-2-methyl-, (R)-
• CAS NO: 34182-03-1
• Molecular Formula: C10H16O2
• Molecular Weight: 168.236
• Mol File: 34182-03-1.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-one, 5-(1-hydroxy-1-methylethyl)-2-methyl-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one, 5-(1-hydroxy-1-methylethyl)-2-methyl-, (R)-(34182-03-1)
• EPA Substance Registry System: 2-Cyclohexen-1-one, 5-(1-hydroxy-1-methylethyl)-2-methyl-, (R)-(34182-03-1)

Safety Data

• Hazardous Substances Data: 34182-03-1(Hazardous Substances Data)

Upstream product

• 6485-40-1 (R)-Carvone 
• 32226-54-3 trans-sobrerol 
• 7785-26-4 (-)-α-pinene 
• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 56423-45-1 (4S,8RS)-8,9-epoxy-p-menth-6-en-2-one 
• 7785-70-8 (+)-α-pinene 
• 38235-58-4 trans-sobrerol 
• 375-72-4 Nonafluorobutanesulfonyl fluoride 
• 14575-93-0 isopinocamphone 
• 56711-60-5 3-Acetoxy-pin-2-en 
• 326598-95-2 (1R,3S,4S,5R)-5-acetoxy-3-hydroxy-4-methyl-1-(methoxycarbonyl)cyclohexane 
• 326622-28-0 (4R,6R)-6-acetoxy-1-methyl-4-(methoxycarbonyl)cyclohexene 
• 772-36-1 (4R,6R)-6-hydroxy-4-(1-hydroxyisopropyl)-1-methylcyclohexene 
• 38927-48-9 (-)-2α-Brom-10β-pinan-3-on 

Downstream Products

• 68568-09-2 (2S,5R)-5-(1-Hydroxy-1-methyl-ethyl)-2-methyl-2-pent-4-enyl-cyclohexanone 
• 68524-96-9 (2S,5R)-5-(1-Hydroxy-1-methyl-ethyl)-2-methyl-2-pent-4-ynyl-cyclohexanone 
• 68525-03-1 (2S,5R)-5-Isopropenyl-2-methyl-2-pent-4-ynyl-cyclohexanone 
• 68524-99-2 (2S,5R)-5-Isopropenyl-2-methyl-2-pent-4-enyl-cyclohexanone 
• 499-75-2 carvacrol 
• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 111323-96-7 C₁₇H₂₄N₂O₃S 
• 111323-97-8 C₁₇H₂₄N₂O₃S 
• 212058-35-0 8-Hydroxy-p-menthan-2-on 
• 2437-97-0 (+/-)-4,7,7-trimethyl-6-oxabicyclo<3.2.1>oct-3-ene 
• 38235-58-4 trans-sobrerol 
• 454-77-3 1(S)-5(S)-(+)-cis-sobrerol 

Relevant articles and documents

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Formation of trans-verbenol and verbenone from α-pinene catalysed by immobilised Picea abies cells

Both enantiomers and the raceinate of α-pinene were transformed by Picea abies cells immobilised on alginate. The main products were cis- and trans-verbenol, the later being further transformed to verbenone. The enantiomeric purity of each product more or less corresponded to that of the substrate. Transformation by free cells was faster than that by the immobilised cells. The ratio of products differed to some extent between the transformation by tree and immobilised cells.

Palladium-catalyzed aerobic oxidative kinetic resolution of alcohols with an achiral exogenous base

Substitution of exogenous (-)-sparteine for a more practical achiral base in the aerobic oxidative kinetic resolution of secondary alcohols is described. Carbonate bases are the most effective of those screened and allow for effective kinetic resolution of benzylic, allylic, and aliphatic substrates. The procedure was also successfully extended to the oxidative desymmetrization of meso diols.