34186-86-2

Basic information

• Product Name: ethyl methyl(tosyloxy)carbamate
• Synonyms: ethyl methyl(tosyloxy)carbamate
• CAS NO: 34186-86-2
• Molecular Weight: 273.31
• Mol File: 34186-86-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl methyl(tosyloxy)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl methyl(tosyloxy)carbamate(34186-86-2)
• EPA Substance Registry System: ethyl methyl(tosyloxy)carbamate(34186-86-2)

Safety Data

• Hazardous Substances Data: 34186-86-2(Hazardous Substances Data)

Upstream product

• 3016-84-0 ethyl hydroxyl(methyl)carbamate 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 34186-84-0 [7-chloro-5-(2-chloro-phenyl)-2-oxo-2,3-dihydro-benzo[e][1,4]diazepin-1-ylmethyl]-carbamic acid ethyl ester 

Relevant articles and documents

A Class of N-O-Type Oxidants to Access High-Valent Palladium Species

This article presents a new class of mild reagents that is capable of oxidizing palladacycle(II) complexes to high-valent palladium species, promoting the formation of C-N bonds in stoichiometric and catalytic conditions. The weak N-O bond and the extremely electron-withdrawing benzenesulfonate group on the oxygen atom of the oxidant are crucial moieties to ensure the desired activity. The oxidation mechanism could involve outer-sphere single-electron transfer processes, opening the possibility for a complementary reactivity of Pd(IV) species.