3016-84-0

Basic information

• Product Name: ethyl hydroxy(methyl)carbamate
• Synonyms: Carbamic acid, hydroxymethyl-, ethyl ester; Ethyl hydroxymethylcarbamate
• CAS NO: 3016-84-0
• Molecular Formula: C₄H₉NO₃
• Molecular Weight: 119.1192
• Mol File: 3016-84-0.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 166.2°C at 760 mmHg
• Flash Point: 54.3°C
• Density: 1.158g/cm³
• Vapor Pressure: 0.6mmHg at 25°C
• Refractive Index: 1.449
• CAS DataBase Reference: ethyl hydroxy(methyl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl hydroxy(methyl)carbamate(3016-84-0)
• EPA Substance Registry System: ethyl hydroxy(methyl)carbamate(3016-84-0)

Safety Data

• Hazardous Substances Data: 3016-84-0(Hazardous Substances Data)

Upstream product

• 593-77-1 N-Methylhydroxylamine 
• 541-41-3 chloroformic acid ethyl ester 
• 589-41-3 ethyl N-hydroxylcarbamate 
• 74-88-4 methyl iodide 
• 4229-44-1 N-methylhydroxyamine hydrochloride 

Downstream Products

• 83176-90-3 benzoyloxy-methyl-carbamic acid ethyl ester 
• 32322-58-0 C₁₁H₁₃ClN₂O₄ 
• 133146-78-8 N-methyl-N-cyclopentyloxyurethane 
• 474510-45-7 (N-methyl-N-methoxyethoxy)carbamic acid ethyl ester 
• 34186-86-2 ethyl methyl(tosyloxy)carbamate 
• 91247-68-6 N-benzyloxy-N-methylcarbamic acid ethyl ester 
• 32322-59-1 C₁₁H₁₃ClN₂O₄ 
• 1500-32-9 2-Methyl-4-phenyl-1,2,4-oxadiazolidin-3,5-dione 

Relevant articles and documents

A Class of N-O-Type Oxidants to Access High-Valent Palladium Species

This article presents a new class of mild reagents that is capable of oxidizing palladacycle(II) complexes to high-valent palladium species, promoting the formation of C-N bonds in stoichiometric and catalytic conditions. The weak N-O bond and the extremely electron-withdrawing benzenesulfonate group on the oxygen atom of the oxidant are crucial moieties to ensure the desired activity. The oxidation mechanism could involve outer-sphere single-electron transfer processes, opening the possibility for a complementary reactivity of Pd(IV) species.