3419-02-1

Basic information

• Product Name: p-Mentha-1(6),8-diene-4-ol
• Synonyms: Limonene-4-ol;p-Mentha-1(6),8-diene-4-ol;p-Mentha-1,8-dien-4-ol;Mentha-1,8-dien-4-ol
• CAS NO: 3419-02-1
• Molecular Formula: C₁₀H₁₆O
• Molecular Weight: 152.23
• Mol File: 3419-02-1.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: p-Mentha-1(6),8-diene-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: p-Mentha-1(6),8-diene-4-ol(3419-02-1)
• EPA Substance Registry System: p-Mentha-1(6),8-diene-4-ol(3419-02-1)

Safety Data

• Hazardous Substances Data: 3419-02-1(Hazardous Substances Data)

Upstream product

• 4584-23-0 2,2,6-trimethyl-1-oxa-spira[2.5]oct-ene 
• 586-62-9 Terpinolene 
• 5259-65-4 4-methyl-3-cyclohexen-1-one 
• 13291-18-4 isopropenylmagnesium bromide 
• 82873-58-3 1-acetyl-4-methyl-3-cyclohexen-1-ol 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 5718-78-5 p-4⁽⁸⁾-Menthene oxide 
• 5535-48-8 PVS 
• 76380-14-8 phenyl 2-propenyl sulfone 

Downstream Products

• 18368-95-1 p-mentha-1,3,8-triene 
• 28233-65-0 1-isopropenyl-4-methyl-1,4-cyclohexadiene 
• 53586-54-2 4-Isopropenyl-1-methyl-1-cyclohexenyl-⁽⁴⁾-vinylether 
• 496808-23-2 4-[(E/Z)-1,5-dimethylhex-5-enylidene]-1-methylcyclohex-1-ene 
• 562-74-3 TERPINEN-4-OL 

Relevant articles and documents

PROCESS FOR PREPARING A MIXTURE OF TERPENE ALCOHOLS

The present invention relates to a process for preparing a mixture of terpene alcohols comprising limonene-4-ol and terpinene-4-ol from terpinolene epoxide via an isomerization and/or hydrogenation reaction in the presence of a copper catalyst.

A PROCESS FOR THE PREPARATION OF LIMONENE-4-OL

The present invention relates to a process for the preparation of limonene-4-ol by an epoxide ring opening isomerization of terpinolene epoxide.

Radical titanocene promoted coupling of epoxides and vinyl sulfones

A radical coupling reaction of diverse vinyl sulfones and epoxides was mediated by Cp2TiCl (Cp = cyclopentadienyl) to provide a straightforward synthetic pathway to hydroxy sulfones. The reaction was successfully achieved by using either an excess or a catalytic amount of the TiIII reagent. The scope of the reaction was studied for several different functionalized and substituted epoxides and vinyl sulfones.

1-Acetyl-4-methyl-3-cyclohexen-1-ol, a useful precursor in the synthesis of cyclic monoterpenes

A synthesis of monocyclic monoterpenes: p-mentha-1,8-dien-4-ol (1), terpinolene (4) and p,α-dimethylstyrene (5) from the titled compound 7, as a common precursor, is reported.

Acid-catalysed Rearrangement of Terpinolene Oxide

The title reaction has been examined in detail and the effects of solvent and the acid catalyst on the nature of the products elucidated.Novel 1,3-dioxolanes, with potential use as aroma chemicals, have been prepared from terpinolene oxide (2) by an efficient method.