3419-02-1Relevant articles and documents
PROCESS FOR PREPARING A MIXTURE OF TERPENE ALCOHOLS
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Page/Page column 13, (2017/09/15)
The present invention relates to a process for preparing a mixture of terpene alcohols comprising limonene-4-ol and terpinene-4-ol from terpinolene epoxide via an isomerization and/or hydrogenation reaction in the presence of a copper catalyst.
Radical titanocene promoted coupling of epoxides and vinyl sulfones
Fernndez-Mateos, Alfonso,Encinas-Madrazo, Soledad,Herrero-Teijn, Pablo,Gonzlez, Rosa Rubio
, p. 548 - 555 (2015/01/30)
A radical coupling reaction of diverse vinyl sulfones and epoxides was mediated by Cp2TiCl (Cp = cyclopentadienyl) to provide a straightforward synthetic pathway to hydroxy sulfones. The reaction was successfully achieved by using either an excess or a catalytic amount of the TiIII reagent. The scope of the reaction was studied for several different functionalized and substituted epoxides and vinyl sulfones.
1-Acetyl-4-methyl-3-cyclohexen-1-ol, a useful precursor in the synthesis of cyclic monoterpenes
Andrade,Munoz,Tamariz
, p. 1603 - 1609 (2007/10/02)
A synthesis of monocyclic monoterpenes: p-mentha-1,8-dien-4-ol (1), terpinolene (4) and p,α-dimethylstyrene (5) from the titled compound 7, as a common precursor, is reported.