34212-65-2Relevant articles and documents
Highly stereoselective synthesis of 2'-deoxy-α-ribonucleosides and 2-deoxy-α-C-ribofuranosides by remote stereocontrolled glycosylation
Mukaiyama, Teruaki,Ishikawa, Tatsuya,Uchiro, Hiromi
, p. 389 - 390 (2007/10/03)
A new and efficient method for catalytic highly α-selective N-and C-glycosylations of 2-deoxyribose derivative with various trimethylsilylated nucleophiles was successfully developed by utilizing effective remote stereocontrol with 5-O-diethylthio carbamo
A NEW SYNTHETIC METHOD FOR γ-BUTYROLACTOLS BY THE PALLADIUM-CATALYZED REGIOSELECTIVE OXIDATION OF 1-ALKEN-4-OLS
Nokami, Junzo,Ogawa, Hideki,Miyamoto, Shinya,Mandai, Tadakatsu,Wakabayahi, Shoji,Tsuji, Jiro
, p. 5181 - 5184 (2007/10/02)
3-substituted 1-alken-4-ols were oxidized with PdCl2-benzoquinone regioselectively at the terminal carbon to afford cyclic hemiacetals (γ-butyroacetols), which were converted to γ-butiroacetones by the Jones oxidation.This reactions was applied to the synthesis of optically active deoxyribose and γ-butenolides.