34212-65-2Relevant academic research and scientific papers
Highly stereoselective synthesis of 2'-deoxy-α-ribonucleosides and 2-deoxy-α-C-ribofuranosides by remote stereocontrolled glycosylation
Mukaiyama, Teruaki,Ishikawa, Tatsuya,Uchiro, Hiromi
, p. 389 - 390 (2007/10/03)
A new and efficient method for catalytic highly α-selective N-and C-glycosylations of 2-deoxyribose derivative with various trimethylsilylated nucleophiles was successfully developed by utilizing effective remote stereocontrol with 5-O-diethylthio carbamo
Chemistry of L-Ascorbic and D-Isoascorbic Acids. An Efficient Synthesis of 2-Deoxypentofuranoses
Vargeese, Chandra,Abushanab, Elie
, p. 4400 - 4403 (2007/10/02)
L-Ascorbic and D-isoascorbic acids have been converted to methyl 3-O-benzyl-2-deoxypentofuranosides.The synthetic routes are enantiospecific, efficient, and economic and proceed in high yields.
A NEW SYNTHETIC METHOD FOR γ-BUTYROLACTOLS BY THE PALLADIUM-CATALYZED REGIOSELECTIVE OXIDATION OF 1-ALKEN-4-OLS
Nokami, Junzo,Ogawa, Hideki,Miyamoto, Shinya,Mandai, Tadakatsu,Wakabayahi, Shoji,Tsuji, Jiro
, p. 5181 - 5184 (2007/10/02)
3-substituted 1-alken-4-ols were oxidized with PdCl2-benzoquinone regioselectively at the terminal carbon to afford cyclic hemiacetals (γ-butyroacetols), which were converted to γ-butiroacetones by the Jones oxidation.This reactions was applied to the synthesis of optically active deoxyribose and γ-butenolides.
2-deoxypentose derivatives
-
, (2008/06/13)
PAF analogues derived from 2-deoxyribose or 2-deoxyxylose, having cytotoxic, hypotensive and PAF agonist/antogonist properties.
