3422-04-6Relevant academic research and scientific papers
Metal free oxidative coupling of aryl formamides with alcohols for the synthesis of carbamates
Reddy, N. Veera,Prasad, K. Rajendra,Reddy, P. Sudhir,Lakshmi Kantam,Reddy, K. Rajender
supporting information, p. 2172 - 2175 (2014/04/03)
A direct transformation of N-aryl formamides to the corresponding carbamates via the formation of isocyanate intermediates is achieved in good yields using hypervalent iodine as an oxidant. This journal is
2-chloro-1,3-dimethylimidazolinium chloride. 3. Utility for chlorination, oxidation, reduction, and rearrangement reactions
Isobe, Toshio,Ishikawa, Tsutomu
, p. 5832 - 5835 (2007/10/03)
2-Chloro-1,3-dimethylimidazolinium chloride (1), which can act as a powerful dehydrating equivalent to DCC (2), is also applicable to chlorination, oxidation, reduction, and rearrangement under nearly neutral conditions. The utility of 1 for these reactions is described.
A CONVENIENT LEWIS ACID CATALYZED PREPARATION OF CARBAMATES FROM SECONDARY ALKOHOLS AND ISOCYANATES
Ibuka, Toshiro,Chu, Gil-Namg,Aoyagi, Takeshi,Kitada, Kazuko,Tsukida, Takahiro,Yoneda, Fumio
, p. 451 - 454 (2007/10/02)
The Lewis acids have been found to be highly effective catalysts for the carbamate formation from secondary alcohols and isocyanates.KEYWORDS - Lewis acid; secondary alcohol; isocyanate; carbamate; γ-carbamoyloxy-α,β-enoate
