342607-12-9

Basic information

• Product Name: benzoic acid 4-hydroxy-4-methyl-(1R)-[(4S)-methyl-5-(triisopropyl-silanyloxy)-pentyl]-pent-2-ynyl ester
• Synonyms: benzoic acid 4-hydroxy-4-methyl-(1R)-[(4S)-methyl-5-(triisopropyl-silanyloxy)-pentyl]-pent-2-ynyl ester
• CAS NO: 342607-12-9
• Molecular Weight: 474.756
• Mol File: 342607-12-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: benzoic acid 4-hydroxy-4-methyl-(1R)-[(4S)-methyl-5-(triisopropyl-silanyloxy)-pentyl]-pent-2-ynyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: benzoic acid 4-hydroxy-4-methyl-(1R)-[(4S)-methyl-5-(triisopropyl-silanyloxy)-pentyl]-pent-2-ynyl ester(342607-12-9)
• EPA Substance Registry System: benzoic acid 4-hydroxy-4-methyl-(1R)-[(4S)-methyl-5-(triisopropyl-silanyloxy)-pentyl]-pent-2-ynyl ester(342607-12-9)

Safety Data

• Hazardous Substances Data: 342607-12-9(Hazardous Substances Data)

Upstream product

• 13154-24-0 triisopropylsilyl chloride 
• 219990-11-1 (R,R)-N-(2-hydroxy-1-methyl-2-phenylethyl)-N-2-(S)-dimethyl-6-hepteneamide 
• 342607-10-7 triisopropyl-((2S)-methyl-hept-6-enyloxy)-silane 
• 342607-11-8 (5S)-methyl-6-(triisopropyl-silanyloxy)-hexanal 
• 115-19-5 2-methyl-but-3-yn-2-ol 
• 98-88-4 benzoyl chloride 
• 1028269-23-9 (5R,9S)-2,9-Dimethyl-10-triisopropylsilanyloxy-dec-3-yne-2,5-diol 

Downstream Products

• 342607-31-2 benzoic acid (1R)-[(4S)-methyl-5-(triisopropyl-silanyloxy)-pentyl]-prop-2-ynyl ester 
• 152044-53-6 epithilone A 

Relevant articles and documents

Stereoselective syntheses of epothilones A and B via directed nitrile oxide cycloaddition

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Discovery and study of new reaction chemistry; applications in complex molecule assembly

The catalytic, in situ generation of metal alkynilides under conditions compatible with electrophilic reaction partners provides fresh avenues for the development of new efficient asymmetric processes leading to C-C bond-formation. We have documented that