342646-89-3

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 139-85-5 3,4-dihydroxybenzaldehyde 
• 331-39-5 caffeic acid 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 99815-16-4 3,4-bis(tert-butyldimethylsilanyloxy)benzaldehyde 

Downstream Products

• 1282616-22-1 C₄₁H₇₀O₃SSi₂ 
• 1282616-24-3 C₂₉H₄₂O₃S 
• 1282616-26-5 C₂₉H₄₂O₄S 
• 1282616-29-8 C₃₀H₄₄O₄S 
• 1352754-68-7 2-[3,4-bis((dimethyl-tert-butylsilyl)oxy)phenyl]-5-(benzyloxy)-2,3-dihydro-8-methoxy-6-methylbenzo[b][1,4]oxathiine 
• 1627688-32-7 C₃₂H₅₄O₄SSi₃ 
• 1627688-34-9 C₂₇H₄₂O₄SSi₂ 
• 1627688-36-1 C₃₂H₅₄O₄SSi₃ 
• 958463-44-0 C₃₅H₆₀O₄SSi₃ 
• 958463-41-7 C₃₄H₅₈O₄SSi₃ 
• 141632-15-7 (E)-3-(3,4-dihydroxyphenyl)acrylaldehyde 
• 865541-48-6 2-[3,4-bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-2,3-dihydro-5,7-dimethoxy-1,4-benzoxathiin 
• 865541-49-7 5,7-bis-(tert-butyl-dimethyl-silanyloxy)-2-[3,4-bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-2,3-dihydro-1,4-benzoxathiin 

Relevant academic research and scientific papers

Ambivalent adhesives: Combining biomimetic cross-linking with antiadhesive Oligo(ethylene glycol)

Oligo(ethylene glycol) (OEG) and poly(ethylene glycol) (PEG) exhibit several desirable properties including biocompatibility and resistance to fouling by protein adsorption. Still needed are surgical glues and orthopedic cements, among several other mater

Bio-based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes

A series of bio-based vinylphenols or hydroxystyrenes is prepared by simple decarboxylation of various naturally occurring cinnamic acids such as o-, m-, and p-coumaric; caffeic; ferulic; and sinapinic acids, which possess hydroxy groups and other substituents at different positions on the aromatic ring. After protection of the phenolic moieties with trialkylsilyl groups, reversible addition–fragmentation chain-transfer polymerization is accomplished with cumyl dithiobenzoate to afford various bio-based hydroxyl-protected polystyrenes with controlled molecular weights and narrow molecular weight distributions. Subsequent deprotection of the silyl groups under mild conditions results in a series of well-defined functionalized polystyrenes possessing different numbers (mono-, di-, tri-) of hydroxy groups at different positions (o, m, p). The obtained functionalized polystyrenes show unique thermal properties depending on the substituents, and those with phenol and catechol groups serve as reducing agents for silver ions.

ANIONIC POLYMERIZATION INITIATORS AND PROCESSES

A group of compounds defined by the general formula (I) can be used to anionically initiate polymerization of unsaturated monomers. In the formula, M is an alkali metal atom, R1 is an aryl group having at least one OR2 substituent gr

HYDROXYARYL FUNCTIONALIZED POLYMERS

Vulcanizates with desirable properties can be obtained from compounds incorporating polymers that include hydroxyl group-containing aryl functionalities. The functionalities can be incorporated by using any or all of appropriate initiators, monomers and o

The kulinkovich reaction in the synthesis of constrained N,N-dialkyl neurotransmitter analogues

An intermolecular Ti(IV)-mediated cyclopropanation reaction has been used to synthesize substituted 2-phenylcyclopropylamines and constrained analogues of the neurotransmitters histamine and tryptamine. Many hydroxy- and methoxy-substituted phenylcyclopropylamines are known to inhibit monoamine oxidase and have been shown to mimic hallucinogens. These compounds were made in 1 to 5 steps from readily available starting materials.