34267-03-3Relevant articles and documents
ETUDE CINETIQUE DE L'AMINOLYSE EN MILIEU NON AQUEUX D'ESTERS MODELES DE PEPTIDYL-t-ARN; INFLUENCE D'UN GROUPE HYDROXYLE VOISIN
Julia, Marc,Mestdagh, Helene
, p. 327 - 337 (2007/10/02)
n-Butylaminolysis of cis 2-hydroxy-cyclopentyl benzoylglycinate (a simple model of peptidyl-t-RNA) in MeCN occurs ca 300 times faster than that of cyclopentyl benzoylglycinate.This acceleration caused by the neighbouring cis 2-hydroxy group is considerabl