34281-44-2

Basic information

• Product Name: 2-bromo-3-phenylbenzo[b]thiophene
• Synonyms: 2-bromo-3-phenylbenzo[b]thiophene
• CAS NO: 34281-44-2
• Molecular Weight: 289.195
• Mol File: 34281-44-2.mol

Chemical Properties

• CAS DataBase Reference: 2-bromo-3-phenylbenzo[b]thiophene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-3-phenylbenzo[b]thiophene(34281-44-2)
• EPA Substance Registry System: 2-bromo-3-phenylbenzo[b]thiophene(34281-44-2)

Safety Data

• Hazardous Substances Data: 34281-44-2(Hazardous Substances Data)

Upstream product

• 98-80-6 phenylboronic acid 
• 14315-12-9 3-phenyl-1-benzothiophene 
• 7342-82-7 3-Bromothianaphthene 
• 591-51-5 phenyllithium 
• 105230-43-1 2,2,2-trifluoroethyl 2-bromophenyl thioether 

Downstream Products

• 849403-86-7 2-fluoro-3-phenylbenzo[b]thiophene 

Relevant articles and documents

Halocarbon Chemistry. 3. Ortho Metallation-Induced Cyclization of Acetylenes: One-Flask Synthesis of 2,3-Disubstituted Benzofurans, Thianaphthenes, and Indoles

A new base-induced cyclization is described which involves the direct one-pot conversion of trifluoroethyl phenyl ethers, thioethers, and amines, in the presence of 4 equiv of alkyl- or aryllithium reagents, to 2,3-disubstituted benzofurans, thianaphthene

In-Depth Assessment of the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides

A thorough investigation of the challenging Pd-catalyzed fluorination of five-membered heteroaryl bromides is presented. Crystallographic studies and density functional theory (DFT) calculations suggest that the challenging step of this transformation is