3433-16-7Relevant articles and documents
Ring strain-promoted allylic transposition of cyclic silyl ethers
Volchkov, Ivan,Park, Sangho,Lee, Daesung
supporting information; experimental part, p. 3530 - 3533 (2011/09/15)
Relief of the ring strain of medium-sized rings promotes a regioselective allylic transposition of a C-O bond when catalyzed by rhenium oxide. Through the allylic transposition, eight-membered cyclic silyl ethers undergo ring contraction to the corresponding six-membered siloxacycles.