343313-84-8

Basic information

• Product Name: 7-(3,5-di-tert-butylphenyl)2,12-bis-[2,2';6',2'']terpyridin-4'-yl-5,6,8,9-tetrahydro-dibenzo[c,h]acridine
• Synonyms: 7-(3,5-di-tert-butylphenyl)2,12-bis-[2,2';6',2'']terpyridin-4'-yl-5,6,8,9-tetrahydro-dibenzo[c,h]acridine
• CAS NO: 343313-84-8
• Molecular Weight: 934.199
• Mol File: 343313-84-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 7-(3,5-di-tert-butylphenyl)2,12-bis-[2,2';6',2'']terpyridin-4'-yl-5,6,8,9-tetrahydro-dibenzo[c,h]acridine(CAS DataBase Reference)
• NIST Chemistry Reference: 7-(3,5-di-tert-butylphenyl)2,12-bis-[2,2';6',2'']terpyridin-4'-yl-5,6,8,9-tetrahydro-dibenzo[c,h]acridine(343313-84-8)
• EPA Substance Registry System: 7-(3,5-di-tert-butylphenyl)2,12-bis-[2,2';6',2'']terpyridin-4'-yl-5,6,8,9-tetrahydro-dibenzo[c,h]acridine(343313-84-8)

Safety Data

• Hazardous Substances Data: 343313-84-8(Hazardous Substances Data)

Upstream product

• 111773-13-8 7-Bromo-1,2,3,4-tetrahydronaphthalene-1-spiro-2'-(1',3'-dioxacyclopentane) 
• 343313-86-0 7-[2,2',6',2'']terpyridin-4'-yl-1,2,3,4-tetrahydronaphthalene-1-spiro-2'-(1',3'-dioxacyclopentane) 
• 6340-79-0 4-oxo-4-(4-bromophenyl)butanoic acid 
• 35656-89-4 4-(4-bromophenyl)butanoic acid 
• 32281-97-3 7-bromo-3,4-dihydro-2H-naphthalen-1-one 
• 108-86-1 bromobenzene 
• 343313-87-1 7-[4'-[2,2';6',2'']terpyridine]-3,4-dihydro-2H-naphthalen-1-one 

Downstream Products

• 343313-85-9 7-(3,5-di-tert-butylphenyl)-2,12-bis-[2,2';6',2'']terpyridin-4'-yl-dibenzodibenzo[c,h]acridine 

Relevant articles and documents

Supramolecular chemistry: Molecular recognition and self-assembly using rigid spacer-chelators bearing cofacial terpyridyl palladium(II) complexes separated by 7 A

Partially and fully aromatic molecular spacers bearing two symmetrically bound terpyridyl chelators have been prepared. These spacer-chelators were constructed to dispose the two terpyridyl ligands and their complexes with square planar metals cofacially with a separation of about 7 A between the two metals. Dipalladium(II) complexes of these spacer-chelators were prepared and characterized. These palladium complexes readily form large molecular rectangles with a linear linker such as 4,4′-dipyridyl. The dichlorodipalladium complex of the partially reduced spacer-chelator is capable of incarcerating planar aromatic and coordination compounds as guests. A crystal structure showing the incorporation of 9-methylanthracene has been determined. A 9-methylanthracene lies completely within the 7 A space provided by the cleft formed by the two cofacially disposed chloro-palladium-terpyridyl units. The crystal structure shows additional π-stacking interactions between a second 9-methylanthracene and neighboring receptors.