343315-86-6

Upstream product

• 676241-01-3 Acetic acid (2R,3R,4R,5S,6S)-3,4,5-tris-benzyloxy-6-vinyl-tetrahydro-pyran-2-ylmethyl ester 
• 112219-66-6 (2R,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-2-(benzyloxymethyl)-6-vinyltetrahydro-2H-pyran 
• 98-59-9 p-toluenesulfonyl chloride 
• 676241-03-5 ((2R,3R,4R,5S,6S)-3,4,5-Tris-benzyloxy-6-vinyl-tetrahydro-pyran-2-yl)-methanol 

Downstream Products

• 343315-92-4 ((1R,2S,3R,4R,5S)-2,3,4-Tris-benzyloxy-5-methoxy-cyclooctyl)-methanol 
• 343315-91-3 ((1S,2S,3R,4R,5S)-2,3,4-Tris-benzyloxy-5-methoxy-cyclooctyl)-methanol 
• 343315-90-2 (1S,2R,3R,4R)-2,3,4-tribenzyloxy-1-methoxy-5-methylenecyclooctane 
• 343315-88-8 (1R,2S,3R,4R,5S)-2,3,4-tribenzyloxy-5-methoxycycloocta-1-ol 
• 343315-89-9 (2R,3S,4S,5S)-2,3,4-tribenzyloxy-5-methoxycyclooctan-1-one 
• 261956-04-1 3,7-anhydro-4,5,6-tri-O-benzyl-1,2,8-trideoxy-D-gulo-oct-1,7-dienitol 

Relevant academic research and scientific papers

Synthesis of several members of a new family of carbasugars: The cyclooctane mimetics

The TIBAL-promoted Claisen rearrangement of carbohydrates, developed in our group, has been applied to vinyl glycosides derived from D-glucose to afford highly functionalized cyclooctene derivatives in a stereospecific manner. Subsequent manipulation of these compounds gave access to a new family of carbasugars: the glucose and idose cyclooctanic mimetics.