343372-29-2

Usage

Molecular Structure

Cyclic structure containing three sulfur atoms, two nitrogen atoms, and one oxygen atom

Class

Hetrocyclic organic compounds

Characteristic

Presence of at least one heteroatom in the ring structure

Chemical Properties

Not well documented

Potential Applications

Not well documented, but its unique molecular structure suggests it may have the potential to interact with other chemicals in a variety of ways

Further Research

Needed to fully understand the properties and uses of 1,7,13-Trithia-4,10-diazacyclohexadecan-15-ol

Upstream product

• 122023-94-3 2-hydroxymethyl-7,14-diaza-1,4,10-trithiacyclopentadecane 
• 226211-71-8 bis<2-(α-chloroacetamido)ethyl> sulfide 
• 343372-27-0 3-hydroxymethyl-7,13-diaza-1,4,10-trithiacyclopentadecane-6,14-dione 

Relevant academic research and scientific papers

Bis-8-hydroxyquinoline-armed diazatrithia-15-crown-5 and diazatrithia-16-crown-5 ligands: Possible fluorophoric metal ion sensors

The synthesis and preliminary photophysical properties of a series of diazatrithia-15-crown-5 and diazatrithia-16-crown-5 ligands containing two 8-hydroxyquinoline sidearms are reported. The ligands were prepared by a two-step process. First, diazatrithiacrown ethers 11 and 12 were prepared by treating bis(α-chloroamide) 5 with various dimercaptans followed by reduction using a boron-THF complex. Hydroxymethyl-substituted macrocycle 12 was rearranged to hydroxy-substituted diazatrithia-16-crown-5 in refluxing aqueous HCl. Macrocyclic diamines 11-13 were converted to either 5-chloro-8-hydroxyquinolin-7-ylmethyl-substituted diazatrithiacrown ethers 14-16 by a Mannich aminomethylation reaction or to 8-hydroxyquinolin-2-ylmethyl-substituted diazatrithiacrown ethers 17-19 by reductive amination using 8-hydroxyquinoline-2-carboxaldehyde. Preliminary photophysical studies show that ligands 16 and 19 exhibit increased fluorescence in the presence of Zn2+, indicating that these ligands could be chemical sensors for Zn2+.