34340-09-5 Usage
General Description
The chemical ".alpha.-D-Glucopyranoside, methyl 6-deoxy-6-iodo-, 3,4-dibenzoate 2-(4-methylbenzenesulfonate)" is a complex compound containing a sugar molecule (glucopyranoside) attached to a methyl ester (6-deoxy-6-iodo-) and two benzoate groups. It also contains a 4-methylbenzenesulfonate moiety. .alpha.-D-Glucopyranoside, methyl 6-deoxy-6-iodo-, 3,4-dibenzoate 2-(4-methylbenzenesulfonate) likely has a wide range of potential applications in organic chemistry, biochemistry, and pharmaceuticals, as it contains a sugar molecule, which can be useful for the development of new drugs or as a building block for other chemical compounds. Additionally, the presence of the 6-deoxy-6-iodo- and benzoate groups suggest potential reactivity and functionalization that could be valuable in synthetic chemistry.
Check Digit Verification of cas no
The CAS Registry Mumber 34340-09-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,4,3,4 and 0 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 34340-09:
(7*3)+(6*4)+(5*3)+(4*4)+(3*0)+(2*0)+(1*9)=85
85 % 10 = 5
So 34340-09-5 is a valid CAS Registry Number.
InChI:InChI=1/C28H27IO9S/c1-18-13-15-21(16-14-18)39(32,33)38-25-24(37-27(31)20-11-7-4-8-12-20)23(22(17-29)35-28(25)34-2)36-26(30)19-9-5-3-6-10-19/h3-16,22-25,28H,17H2,1-2H3
34340-09-5Relevant articles and documents
A convenient synthesis of orthogonally protected 2-deoxystreptamine (2-DOS) as an aminocyclitol scaffold for the development of novel aminoglycoside antibiotic derivatives against bacterial resistance
Bauder, Claude
supporting information; experimental part, p. 2952 - 2960 (2009/02/02)
The development of new aminoglycoside analogues to reduce the emergence of bacterial resistance has become a topic of high interest. We describe here a rapid and facile access to orthogonally protected 2-deoxystreptamine (2-DOS), a meso-diaminocyclitol known to be a pivotal component of most active aminoglycosides. Our synthetic approach started from highly protected methyl α-d-glucopyranoside which in turn was converted by a Ferrier rearrangement into an enantiopure polyfunctionalized cyclohexane ring. Finally, two different N-protected groups were successively introduced. The first one was inserted as an oximino benzylether followed by a diastereofacial hydride reduction, working with Me4NBH(OAc)3 only in TFA at low temperature rather than in AcOH as usual. The second group was introduced by displacement of a hydroxyl group through a Mitsunobu reaction using a DPPA-DIAD-Ph3P system for azide transfer. The Royal Society of Chemistry.