80675-64-5

Basic information

• Product Name: 3-Cyclopentene-1,2-diol, 5-(hydroxymethyl)-, 1,2-dibenzoate, 1R-(1.alpha.,2.beta.,5.beta.)-
• Synonyms: 3-Cyclopentene-1,2-diol, 5-(hydroxymethyl)-, 1,2-dibenzoate, 1R-(1.alpha.,2.beta.,5.beta.)-
• CAS NO: 80675-64-5
• Molecular Formula: C₂₀H₁₈O₅
• Molecular Weight: 338.35
• Mol File: 80675-64-5.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Cyclopentene-1,2-diol, 5-(hydroxymethyl)-, 1,2-dibenzoate, 1R-(1.alpha.,2.beta.,5.beta.)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclopentene-1,2-diol, 5-(hydroxymethyl)-, 1,2-dibenzoate, 1R-(1.alpha.,2.beta.,5.beta.)-(80675-64-5)
• EPA Substance Registry System: 3-Cyclopentene-1,2-diol, 5-(hydroxymethyl)-, 1,2-dibenzoate, 1R-(1.alpha.,2.beta.,5.beta.)-(80675-64-5)

Safety Data

• Hazardous Substances Data: 80675-64-5(Hazardous Substances Data)

Upstream product

• 80685-07-0 (1R,5R)-6-exo,7-endo-dibenzoyloxy-N-methyl-8-exo-tosyloxy-3-oxa-2-azabicyclo<3.3.0>octane 
• 80675-62-3 (2R,3S,4R)-3,4-bis-O-benzoyloxy-2-O-toluene-p-sulfonylhex-5-enal 
• 34340-09-5 3,4-di-O-benzoyl-6-deoxy-6-iodo-2-O-p-toluenesulfonyl-α-D-glucopyranoside 
• 80675-63-4 (1R)-2-endo,3-exo-dibenzoyloxy-4-endo-hydroxymethyl-N-methyl-6-azabicyclo<3.1.0>hexane 

Downstream Products

• 165375-27-9 (1R,2R,3S,4S,5R)-4-(ethoxycarbonylamino)-3-hydroxy-5-(hydroxymethyl)cyclopentane-1,2-diyl dibenzoate 
• 165375-20-2 (1R,2R,3S,4S,5S)-3-(ethoxycarbonylamino)-4-hydroxy-5-(hydroxymethyl)cyclo-pentane-1,2-diyl dibenzoate 
• 165375-22-4 (1S,2S,3R,4R,5S)-3,4-dibenzoyloxy-5-(hydroxymethyl)cyclopentane-1,2-diol 
• 80675-69-0 (1R,5R)-6-exo,7-endo-dibenzoyloxy-8-exo-iodo-3-oxo-2-oxabicyclo<3.3.0>octane 
• 80675-68-9 C₂₁H₁₈O₆ 
• 80675-67-8 3,4-dibenzoyloxy-5-(formylmethyl)cyclopent-1-ene 
• 80735-00-8 (1S,2R,4S,6S)-8-oxo-3,7-dioxatricyclo<4.3.0.0^2,4>nonane 
• 88203-80-9 C₃₅H₃₂N₂O₄ 
• 80675-70-3 (1S,5S)-6-exo,7-endo-dibenzoyloxy-3-oxo-2-oxabicyclo<3.3.0>octane 
• 80675-66-7 C₂₁H₁₇NO₄ 
• 59829-44-6 (1S,2S,4R,6S)-8-oxo-3,7-dioxatricyclo<4.3.0.0^2,4>nonane 
• 158528-74-6 (1S,5S)-3-dimethylamino-8-exo-hydroxymethyl-7-endo-hydroxy-2-oxa-4-azabicyclo<3.3.0>oct-3-en-6-endo-yl 2-acetamido-4-O-(2-acetamido-2-deoxy-β-D-allopyranosyl)-2-deoxy-β-D-allopyranoside 
• 165375-25-7 C₃₃H₄₁NO₈SSi 
• 165375-31-5 (1S,5S)-6-exo,7-endo-dibenzoyloxy-8-exo-benzyloxymethyl-3-dimethylamino-2-oxa-4-azabicyclo<3.3.0>octan-3-ene 

Relevant articles and documents

Functionalised Carbocycles from Carbohydrates. Part 3. The Synthesis of the Epoxy Lactone Prostaglandin Intermediate via an Isoxazolidine Derivative. X-Ray Crystal Structure of (1R,5R)-6-exo,7-endo-Dibenzoyloxy-8-exo-iodo-3-oxo-2-oxabicyclooctane

The bicyclic isoxazolidine 6,7-dibenzoyloxy-N-methyl-8-tosyloxy-3-oxa-2-azabicyclooctane (1), which is easily obtained from a readily available D-glucose derivative, has been converted into the epoxy lactone 8-oxo-3,7-dioxatricyclo2,4>nonane (13), via a series of cyclopentane derivatives, in ten steps.Since the product (13) can be used to prepare prostaglandins this sequence represents a new route to these compounds in their enantiomerically pure natural form.