344-38-7Relevant articles and documents
PROCESS FOR THE PREPARATION OF ORGANIC HALIDES
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Paragraph 00122, (2017/08/01)
The present invention provides a halo-de-carboxylation process for the preparation of organic chlorides, organic bromides and mixtures thereof, from their corresponding carboxylic acids, using a chlorinating agent selected from trichloroisocyanuric acid (TCCA), dichloroisocyanuric acid (DCCA), or combination thereof, and a brominating agent.
Para-Selective Halogenation of Nitrosoarenes with Copper(II) Halides
Van Der Werf, Angela,Selander, Nicklas
supporting information, p. 6210 - 6213 (2016/01/09)
The para-selective direct bromination and chlorination of nitrosoarenes with copper(II) bromide and chloride is reported. Under mild reaction conditions, a range of halogenated arylnitroso compounds are obtained in moderate to good yields with high regioselectivity. Additionally, the versatility of the method is demonstrated by the development of a one-pot procedure to obtain the corresponding para-halogenated aniline- and nitrobenzene derivatives.