34418-84-3Relevant academic research and scientific papers
Silver-promoted decarboxylative sulfonylation of aromatic carboxylic acids with sodium sulfinates
Yu, Yongqi,Wu, Qianlong,Liu, Da,Yu, Lin,Tan, Ze,Zhu, Gangguo
, p. 11195 - 11202 (2019/09/12)
A novel and efficient synthesis of sulfones was developed via a silver-promoted decarboxylative sulfonylation reaction between aromatic carboxylic acids and sodium sulfinates for the first time. The approach features operational simplicity and good functional group compatibility and uses readily available starting materials. Furthermore, mechanistic studies reveal that the decarboxylative sulfonylation reaction is likely to proceed via a radical mechanism.
Convenient one-pot procedure for converting aryl sulfides to nitroaryl sulfones
Nose, Masatoshi,Suzuki, Hitomi
, p. 1065 - 1071 (2007/10/03)
When treated with nitrogen dioxide and ozone in inert solvent at 0°C or below, aryl sulfides underwent smooth oxidative nitration to give nitroaryl sulfones in good yield. Using this methodology, a series of mono- and di-nitrated aryl sulfones were prepared from methyl phenyl sulfide and diphenyl sulfide and their physical data are presented.
