344250-14-2

Basic information

• Product Name: ((3-(cyclohex-1-en-1-yl)propoxy)methyl)benzene
• Synonyms: ((3-(cyclohex-1-en-1-yl)propoxy)methyl)benzene
• CAS NO: 344250-14-2
• Molecular Weight: 230.35
• Mol File: 344250-14-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ((3-(cyclohex-1-en-1-yl)propoxy)methyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: ((3-(cyclohex-1-en-1-yl)propoxy)methyl)benzene(344250-14-2)
• EPA Substance Registry System: ((3-(cyclohex-1-en-1-yl)propoxy)methyl)benzene(344250-14-2)

Safety Data

• Hazardous Substances Data: 344250-14-2(Hazardous Substances Data)

Upstream product

• 82726-01-0 Benzoic acid 3-((1R,2R)-2-hydroxy-cyclohexyl)-propyl ester 
• 65173-43-5 ethyl 3-(cyclohex-1-en-1-yl)propionate 
• 82725-83-5 3-(cyclohex-1-en-1-yl)propyl benzoate 
• 60211-12-3 2-(3-hydroxypropyl)cyclohexan-1-ol 
• 4430-31-3 octahydrocoumarin 
• 22516-18-3 3-(cyclohex-1-en-1-yl)propan-1-ol 
• 100-39-0 benzyl bromide 
• 53067-09-7 cis-2-(3-hydroxypropyl)-cyclohexanol 
• 82726-04-3 Benzoic acid 3-[(1R,2R)-2-(toluene-4-sulfonyloxy)-cyclohexyl]-propyl ester 

Downstream Products

• 344268-52-6 C₁₆H₂₁⁽²⁾HO₂ 
• 82725-85-7 trans-<2-(2)H>-2-(3-Hydroxypropyl)cyclohexanol 
• 82725-85-7 C₉H₁₇⁽²⁾HO₂ 
• 82725-84-6 cis-<2-(2)H>-2-(3-Benzyloxypropyl)cyclohexanol 
• 82725-84-6 trans-<2-(2)H>-2-(3-Benzyloxypropyl)cyclohexanol 

Relevant articles and documents

Enantioselective Hydroazidation of Trisubstituted Non-Activated Alkenes

A one-pot procedure for the enantioselective hydroazidation of non-activated trisubstituted alkenes is described. Hydroboration with monoisopinocampheylborane (IpcBH2) provides dialkylboranes that are in situ selectively converted into monoalkyl-substituted catecholboranes; these undergo radical azidation upon treatment with benzenesulfonyl azide and a radical initiator. Enantiomerically enriched azides were thus obtained in yields of 59–81 % and enantioselectivities of up to 94:6 e.r. (98:2 e.r. if the intermediate dialkylborane is purified by crystallization). A rapid access to enantiomerically pure (+)-rodocaine is also described. The use of other arenesulfonyl radical traps enables enantioselective hydroallylation, hydrosulfanylation, and hydrobromination reactions with yields of 71–86 %.