344403-81-2

Basic information

• Product Name: (2R,3S,4R,5R,6S)-2-(acetoxymethyl)-5-azido-6-((tert-butyldiphenylsilyl)oxy)tetrahydro-2H-pyran-3,4-diyl diacetate
• Synonyms: (2R,3S,4R,5R,6S)-2-(acetoxymethyl)-5-azido-6-((tert-butyldiphenylsilyl)oxy)tetrahydro-2H-pyran-3,4-diyl diacetate
• CAS NO: 344403-81-2
• Molecular Weight: 569.687
• Mol File: 344403-81-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (2R,3S,4R,5R,6S)-2-(acetoxymethyl)-5-azido-6-((tert-butyldiphenylsilyl)oxy)tetrahydro-2H-pyran-3,4-diyl diacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S,4R,5R,6S)-2-(acetoxymethyl)-5-azido-6-((tert-butyldiphenylsilyl)oxy)tetrahydro-2H-pyran-3,4-diyl diacetate(344403-81-2)
• EPA Substance Registry System: (2R,3S,4R,5R,6S)-2-(acetoxymethyl)-5-azido-6-((tert-butyldiphenylsilyl)oxy)tetrahydro-2H-pyran-3,4-diyl diacetate(344403-81-2)

Safety Data

• Hazardous Substances Data: 344403-81-2(Hazardous Substances Data)

Upstream product

• 282526-04-9 methyl 2-azido-2-deoxy-1-thio-β-D-glucopyranoside 
• 146934-27-2 Methyl 2-azido-2-deoxy-3,4,6-tri-O-acetyl-1-thio-α-D-glucopyranoside 
• 171032-74-9 1,3,4,6-tetra-O-acetyl-2-azido-2-deoxy-D-glucopyranose 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 1078691-95-8 (+)-D-glucosamine hydrochloride 

Downstream Products

• 1271131-92-0 4-(N-benzyloxycarbonylamino)-2-azido-3-O-chloroacetyl-2,4,6-trideoxy-β-D-galactopyranose 
• 501088-46-6 tert-butyldiphenylsilyl 2-azido-2-deoxy-β-D-glucopyranoside 
• 1384556-75-5 2-trichloromethyl-4,5-dihydro-(2-azido-2,4,6-trideoxy-1-O-tert-butyldiphenylsilyl-β-D-allopyranoso)[3,4-d]-1,3-oxazole 
• 1384556-72-2 2-trichloromethyl-4,5-dihydro-(2-azido-2,4,6-trideoxy-1-O-tert-butyldiphenylsilyl-β-D-galactopyranoso)[4,3-d]-1,3-oxazole 

Relevant articles and documents

One-Step TEMPO-Catalyzed and Water-Mediated Stereoselective Conversion of Glycals into 2-Azido-2-deoxysugars with a PIFA-Trimethylsilyl Azide Reagent System

An unprecedented water-mediated and TEMPO-catalyzed, one-step, highly regiospecific and stereoselective functionalization of glycals to 2-azido-2-deoxysugars has been developed using a PIFA-Me3SiN3 reagent system in the presence of B

Synthesis of novel, fluorescently tagged analogs of glycosylphosphatidylinositol (GPI) anchors

Glycosylphosphatidylinositol (GPI) anchors are a group of complex glycolipids that attach extracellular proteins and glycoproteins to the eukaryotic cell outer membrane. To better understand GPI anchorage, it is necessary to have access to homogeneous, structurally defined, and functionalized GPIs and GPI analogs. In this regard, chemical synthesis is necessary, as GPI anchors are rather scarce and heterogeneous in natural sources. Three GPI analogs with phosphoglycerolipids linked to the pseudodisaccharide core and their fluorescein conjugates were prepared in this work as a small tool set useful for probing how the lipid composition and carbohydrate anomeric configuration may affect the properties of GPI anchors.