3445-09-8Relevant academic research and scientific papers
Generation of Sulfenate Salts via Ipso-substitution of Azaheterocyclic Sulfoxides. First Preparation and Characterization of Sodium 2-Pyridinesulfenate
Furukawa, Naomichi,Konno, Yasuo,Tsuruoka, Masayuki,Fujihara, Hisashi,Ogawa, Satoshi
, p. 1501 - 1504 (2007/10/02)
2-Alkyl- or 2-aryl-sulfinylpyridine N-oxides undergo ipsosubstitution reaction with sodium ethoxide to afford sodium sulfenates which were converted soon to the corresponding sulfinates upon contact with oxygen.Sodium 2-pyridinesulfenate was prepared and characterized by FT-IR as the first example of stable sulfenate.
A CONVENIENT PREPARATION OF SULFINIC ACIDS BY THE REACTION OF 2-SULFONYLPYRIDINES AND THEIR N-OXIDES WITH NUCLEOPHILES
Furukawa, Naomichi,Tsuruoka, Masayuki,Fujihara, Hisashi
, p. 3019 - 3022 (2007/10/02)
Ipso-substitution reaction of 2-sulfonylpyridines and their N-oxides with alkoxide or thiolate anion afforded the sodium salts of sulfinic acids together with the corresponding substitution product in high yields.This procedure becomes a convenient and versatile method for preparation of various sulfinic acids.
