344561-54-2Relevant academic research and scientific papers
Synthesis of α-Carbalkoxy Enethiols: A Class of Tautomeric Thiopyruvate Derivatives. Application to Griseoviridin
Butera, John,Rini, Josephine,Helquist, Paul
, p. 3676 - 3678 (2007/10/02)
A general approach to previously inaccessible α-carbalkoxy enethiols 1 is described (e.g., 4 -> 5 -> 6 -> 7), and the use of such substances in synthesis is illustrated (11).
Alkylation and Aldol Condensation Reactions of 1,3-Oxathiolanones
McIntosh, John M.,Mishra, Pratibha,Siddiqui, Maqbool A.
, p. 1036 - 1040 (2007/10/02)
Reaction of 2,2,4-trimethyl-1,3-oxathiolan-5-one (1b) with alkyl halides in the presence of LDA and HMPA give alkylation products only with very reactive halides.In contrast, 2,2-dimethyl-1,3-oxathiolan-5-one (1a) affords no alkylation products.Both 1a an
