344575-39-9Relevant academic research and scientific papers
Synthesis of Phenoxyamines
Castellino, Angelo J.,Rapoport, Henry
, p. 1348 - 1352 (2007/10/02)
Treatment of phenols with 2,4-dinitrophenoxyamine leads to the synthesis of phenoxyamines through an amine exchange reaction.Yields for this reaction are sensitive to the pKa of the phenol in a manner explainable in terms of a competing bimolecular decomposition reaction involving the 2,4-dinitrophenoxyamines.By use of an appropriately sustituted phenol, this phenomenon can be exploited to give high yields of phenoxyamines having oxygenated substitution patterns that were unattainable by previous methods.
